Herbicide combination with acylated aminophenylsulfonylureas

ABSTRACT

Herbicidal compositions with acylated aminophenylsulfonylureas 
     Herbicide combinations with an effective content of components (A), (B) and (C) have improved herbicidal effects: 
     (A) one or more herbicides selected from the group of the compounds of the formula (I) or their salts,                    
     (B) denotes one or more herbicides from the group of the compounds of the formula (II) and their salts,                    
     (C) denotes one or more herbicides from the group of the compounds consisting of (C1) flumioxazin (C2) alachlor (C3) metolachlor (C4) acetochlor (C5) dimethenamid (C6) pethoxamid (C7) atrazine (C8) simazone (C9) cyanazine (C10) terbuthylazine (C11) metribuzin (C12) isoxaflutole (C13) fluthiamid (C14) terbutryne (C15) nicosulfuron (C16) rimsulfuron (C17) primsulfuron (C18) pendimethalin (C19) sulcotrione (C20) dicamba (C21) mesotrione (C22) linuron (C23) benoxacor (C24) metosulam (C25) flumetsulam (C26) sethoxydim (C27) cycloxydim (C28) clethodim (C29) clefoxidim (C30) aclonifen (C31) MCPA (C32) 2, 4-D (C33) bromoxynil (C34) bentazone (C35) fluthiacet (C36) pyridate (C37) diflufenzopyr (C38) carfentrazone (C39) clopyralid (C40) halosulfuron (C41) thifensulfuron (C42) prosulfuron (C43) tritosulfuron (C44) sulfosulfuron (C45) ethoxysulfuron (C46) tribenuron (C47) amidosulfuron (C48) mecoprop (C49) dichlorporp (C50) fluroxypyr (C51) profluazol (C52) amicarbazone (C53) trifloxysulfuron (C54) glufosinate (C55) glufosinate-ammonium (C56) glyphosate (C57) glyphosate-isopropytammonium (C58) imazapyr (C59) imazethapyr (C60) imazamethabenz (C61) imazamox (C62) imazaquin and (C63) imazapic (AC 263,222).

DESCRIPTION

Herbicide combination with acylated aminophenylsulfonylureas

The invention is in the technical field of crop protection productswhich can be employed against harmful plants, for example in plantcrops, and which comprise, as active ingredients, a combination of atleast three herbicides.

The publications WO 95/29899 and WO 92/13845 disclose sulfonylureas andtheir salts and also their use as herbicides and/or plant growthregulators.

The efficacy of these herbicides against harmful plants in the plantcrops is at a high level, but depends in general on the applicationrate, the formulation in question, the harmful plants or spectrum ofharmful plants to be controlled in each case, the climatic conditions,the soil conditions and the like. Another criterion is the duration ofaction, or the breakdown rate of the herbicide. If appropriate, changesin the sensitivity of harmful plants, which may occur upon prolonged useof the herbicides or within geographic limitations must also be takeninto consideration. The compensation of losses in action in the case ofindividual harmful plants by increasing the application rates of theherbicides is only possible to a certain degree, for example becausesuch a procedure frequently reduces the selectivity of the herbicides orbecause the action is not improved, even when applying higher rates. Insome cases, the selectivity in crops can be improved by adding safeners.In general, however, there remains a need for methods to achieve theherbicidal action with a lower application rate of active ingredients.Not only does a lower application rate reduce the amount of an activeingredient required for application, but, as a rule, it also reduces theamount of formulation auxiliaries required. It both reduces the economicinput and improves the ecological compatibility of the herbicidetreatment.

One possibility of improving the application profile of a herbicide canconsist in combining the active ingredient with one or more other activeingredients. However, the combined use of a plurality of activeingredients does not infrequently cause phenomena of physical andbiological incompatibility, for example a lack of stability in acoformulation, decomposition of an active ingredient, or antagonism ofthe active ingredients. Desired, in contrast, are combinations ofactive-ingredients with an advantageous activity profile, high stabilityand if possible a synergistically improved action, which allowsreduction of the application rate in comparison with the individualapplication of the active ingredients to be combined.

Surprisingly, it has now been found that certain active ingredients fromthe group of the acylated aminophenylsulfonylureas in combination withcertain structurally different herbicides act together in a particularlyadvantageous manner, for example when they are employed in plant cropswhich are suitable for the selective use of the herbicides, ifappropriate with addition of safeners.

The invention therefore relates to herbicide combinations with aneffective content of components (A), (B) and (C), where

(A) denotes one or more herbicides from the group of the compounds ofthe formula (I) or their salts,

(B) denotes one or more herbicides from the group of the compounds ofthe formula (II) or their salts,

and

(C) denotes one or more herbicides from the group of the compoundsconsisting of (referred to by the “common names” under the reference“The Pesticide Manual” 11th Ed., British Crop Protection Council 1997,abbreviated to “PM”)

(CI) herbicides which are selective in cereals and/or somedicotyledonous crops and act against monocotyledonous and-dicotyledonous harmful plants, which herbicides are selected from thegroup consisting of:

(C1) flumioxazin (PM, pp. 576-577), for exampleN-(7-fluoro-3,4-dihydro-3-oxo-4-prop-2-inyl-2H-1,4-benzoxazin-6-yl)cyclohex-1 -ene-1,2-dicarboxamide, (application rate: 10-500 g AS/ha,preferably 20-400 g AS/ha; application ratio (A+B)/C=1:25-50:1,preferably 1:10-20:1);

(C2) alachlor (PM, pp. 23-24), for example2-chloro-N-(2,6-diethylphenyl)-N-(methoxymethyl)acetamide, (applicationrate: 100-5000 g AS/ha, preferably 300-4000 g AS/ha; application ratio(A+B)/C=1:500-3:1, preferably 1:250-1:1);

(C3) metolachlor (PM, pp.833-834), for example2-chloro-N-(2-ethyl-6-methylphenyl)-N-(2-methoxy-1-methylethyl)acetamide,(application rate: 100-5000 g AS/ha, preferably 300-4000 g AS/ha;application ratio (A+B)/C=1:500-3:1, preferably 1:250-1:1);

(C4) acetochlor (PM, pp. 10-12), for example2-chloro-N-(ethoxymethyl)-N-(2-ethyl-6-methylphenyl)-acetamide,(application rate: 100-5000 g AS/ha, preferably 300-4000 g AS/ha;application ratio (A+B)/C=1:500-3:1, preferably 1:250-1:1);

(C5) dimethenamid (PM, pp. 409-410), for example2-chloro-N-(2,4-dimethyl-3-thienyl)-N-(2-methoxy-1-methylethyl)acetamide,(application rate: 100-5000 g AS/ha, preferably 300-4000 g AS/ha;application ratio (A+B)/C=1:500-3:1, preferably 1:250-1:1);

(C6) pethoxamide (AG Chem, New Compound Review (publ. Agranova), Vol.17,1999, p. 94, for example2-chloro-N-(2-ethoxyethyl)-N-(2-methyl-1-phenyl-1-propenyl)acetamide,(application rate: 100-5000 g AS/ha, preferably 300-4000 g AS/ha;application ratio (A+B)/C=1:500-3:1, preferably 1:250-1:1);

(C7) atrazine (PM, pp. 55-57), for exampleN-ethyl-N-isopropyl-6-chloro-2,4-diamino-1,3,5-triazine, (applicationrate: 100-5000 g AS/ha, preferably 300-4000 g AS/ha; application ratio(A+B)/C=1:500-3:1, preferably 1:250-1:1);

(C8) simazine (PM, pp. 1106-1108), for example6-chloro-N,N-diethyl-2,4-diamino-1,3,5-triazine (application rate:100-5000 g AS/ha, preferably 300-4000 g AS/ha; application ratio(A+B)/C=1:500-3:1, preferably 1:250-1:1);

(C9) cyanazine (PM, pp. 280-283), for example2-(4-chloro-6-ethylamino-1,3,5-triazin-2-ylamino)-2-methylpropionitrile,(application rate: 100-500 9 AS/ha, preferably 300-4000 g AS/ha;application ratio (A+B)/C=1:500-3:1, preferably 1:250-1:1);

(C10) terbuthylazine (PM, pp.1168-1170), for exampleN-ethyl-N-tert-butyl-6-chloro-2,4-diamino-1,3,5-triazine, (applicationrate: 100-5000 g AS/ha, preferably 300-4000 g AS/ha; application ratio(A+B)/C=1:500-3:1, preferably 1:250-1:1);

(C11) metribuzin (PM, pp. 840-841), for example4-amino-6-tert-butyl-3-methylthio-1,2,4-triazin-5(4H)-one, (applicationrate: 10-3000 g AS/ha, preferably 20-2000 g AS/ha; application ratio(A+B)/C=1:300-25:1, preferably 1:100-10:1);

(C12) isoxaflutole (PM, pp. 737-739), for example(5-cyclopropyl-4-isoxazolyl)[2-(methylsulfonyl)-4-(trifluoromethyl)phenyl]methanone,(application rate: 10-3000 g AS/ha, preferably 20-2000 g AS/ha;application ratio (A+B)/C=1:300-25:1, preferably 1:100-10:1);

(C13) fluthiamid (=flufenacet=BAY FOE 5043) (PM, pp. 82-83), for example4′-fluoro-N-isopropyl-2-(5-trifluoromethyl-1,3,4-thiadiazol-2-yloxy)acetanilide,(application rate: 10-3000 g AS/ha, preferably 20-2000 g AS/ha;application ratio (A+B)/C=1:300-25:1, preferably 1:100-10:1);

(C14) terbutryne (PM, pp.1170-1172), for exampleN-(1,1-dimethylethyl)-N-ethyl-6-(methylthio)-1,3,5-triazine-2,4-diamine,(application rate: 10-3000 g AS/ha, preferably 20-2000 g AS/ha;application ratio (A+B)/C=1:500-3:1, preferably 1:250-1:1);

(C15) nicosulfuron (PM, pp. 877-879), for example2-(4,6-dimethoxypyrimidin-2-yl)-3-(3-dimethylcarbamoyl-2-pyridylsulfonyl)ureaand its salts, (application rate: 1-120 g AS/ha, preferably 2-909 AS/ha;application ratio (A+B)C=1:12-240:1, preferably 1:5-100:1);

(C16) rimsulfuron (PM, pp. 1095-1097), for example1-(4,6-dimethoxypyrimidin-2-yl)-3-(3-ethylsulfonyl-2-pyridylsulfonyl)ureaand its salts, (application rate: 1-120 g AS/ha, preferably 2-90 gAS/ha; application ratio (A+B)/C=1:12-240:1, preferably 1:5-100:1);

(C17) primisulfuron, also comprising its esters, such as the methylester (PM, pp. 997-999), for example2-[4,6-bis(difluoromethoxy)pyrimidin-2-ylcarbamoylsulfamoyl]benzoic acidor its methyl ester, and its salts, (application rate: 1-120 g AS/ha,preferably 2-90 g AS/ha; application ratio (A+B)/C=1:12-240:1,preferably 1:5-100:1);

(C18) pendimethalin (PM, pp. 937-939), for exampleN-(1-ethylpropyl)-2,6-dinitro-3,4-xylidine, (application rate: 100-5000g AS/ha, preferably 200-4000 g AS/ha; application ratio(A+B)/C=1:500-3:1, preferably 1:200-1:1);

(C19) sulcotrione (PM, pp. 1124-1125), for example2-(2-chloro-4-mesylbenzoyl)cyclohexane-1,3-dione, (application rate:5-1500 g AS/ha, preferably 10-1000 g AS/ha; application ratio(A+B)/C=1:150-50:1, preferably 1:50-20:1);

(C20) dicamba (PM, pp. 356-357), for example 3,6-dichloro-o-anisic acidand its salts, (application rate: 5-1500 g AS/ha, preferably 10-1000 gAS/ha; application ratio (A+B)/C=1:150-50:1, preferably 1:50-20:1);

(C21) mesotrione, for example2-(4-mesyl-2-nitrobenzoyl)cyclohexane-1,3-dione (ZA 1296, cf. WeedScience Society of America (WSSA) in WSSA Abstracts 1999, Vol. 39, pages65-66, numbers 130-132), (application rate: 5-1500 g AS/ha, preferably10-1000 g AS/ha; application ratio (A+B)/C=1:150-50:1, preferably1:50-20:1);

(C22) linuron (PM, pp. 751-753), for example3-(3,4-dichlorophenyl)-1-methoxy-1-methylurea, (application rate:100-5000 g AS/ha, preferably 200-4000 g AS/ha; application ratio(A+B)/C=1:500-3:1, preferably 1:200-1:1);

(C23) benoxacor (PM, pp.102-103), for example(±)-4-dichloroacetyl-3,4-dihydro-3-methyl-2H-1,4-benzoxazine,(application rate: 5-1500 g AS/ha, preferably 10-1000 g AS/ha;application ratio (A+B)/C=1:150-50:1, preferably 1:50-20:1);

(C24) metosulam (PM, pp. 836-838), for example2′,6′-dichloro-5,7-dimethoxy-3′-methyl[1,2,4]triazolo[1,5-a]pyrimidine-2-sulfonamide,(application rate: 5-1500 g AS/ha, preferably 10-1000 g AS/ha;application ratio (A +B)/C=1:150-50:1, preferably 1:50-20:1);

(C25) flumetsulam (PM, pp. 573-574), for example2′,6′-difluoro-5-methyl[1,2,4]triazolo[1,5-a]pyrimidine-2-sulfonamide,(application rate: 5-1500 g AS/ha, preferably 10-1000 g AS/ha;application ratio (A+B)/C=1:150-50:1, preferably 1:50-20:1);

(C26) sethoxydim (PM, pp.1101-1103), for example(±)-(EZ)-(1-ethoxyiminobutyl)-5-[2-ethylthio)propyl]-3-hydroxycyclohex-2-enone, (application rate: 10-5000 g AS/ha, preferably20-3000 g AS/ha; application ratio (A+B)/C=1:500-25:1, preferably1:150-1:1);

(C27) cycloxydim (PM, pp.290-291), for example(±)-2-[1-ethoxyimino)butyl]-3-hydroxy-5-thian-3-ylcyclohex-2-enone,(application rate: 10-5000 g AS/ha, preferably 20-3000 g AS/ha;application ratio (A+B)/C=1:500-25:1, preferably 1:150-1:1);

(C28) clethodim (PM, pp. 250-251), for example(±)-2-[(E)-1-[(E)-3-chloroallyloxyimino]propyl]-5-[2-(ethylthio)propyl]-3-hydrocyclohex-2-enone,(application rate: 10-5000 g AS/ha, preferably 20-3000 g AS/ha;application ratio (A+B)/C=1:500-25:1, preferably 1:150-1:1);

(C29) clefoxidim, for example2-[1-(2-(4-chlorophenoxy)-propoxyimino)butyl]-3-oxo-5-thion-3-ylcyclohex-1-enol(AG Chem, New Compound Review (publ. Agranova), Vol.17,1999, p. 26),(application rate: 10-5000 g AS/ha, preferably 20-3000 g AS/ha;application ratio (A+B)/C=1:500-25:1, preferably 1:150-1:1);

(CII) herbicides which act selectively in some dicotyledonous cropspredominantly, against dicotyledonous harmful plants, selected from thegroup consisting of

(C30) aclonifen, in particular also including its salts, such as thesodium salt, (PM, pp. 14-15), for example2-chloro-6-nitro-3-phenoxyanilin, (application rate in general: 50-5000g AS/ha, preferably 200-3000 g AS/ha; application ratio(A+B)/C=1:5000-2:1, preferably 1:600-1:3);

(C31) MCPA (PM, pp. 770-771), for example(4-chloro-2-methylphenoxy)acetic acid, predominantly employed forms,inter alia, MCPA-butotyl, MCPA-dimethylammonium, MCPA-isoctyl,MCPA-potassium. MCPA-sodium, (application rate: 50-5000 g AS/ha,preferably 100-3000 g AS/ha; application ratio (A+B)/C=1:500-5:1,preferably 1:150-2:1);

(C32) 2,4-D (PM, pp. 323-327), for example (2,4-dichloro-phenoxy)aceticacid, frequently employed forms: 2,4-D-butotyl, 2,4-D-butyl,2,4-D-dimethylammonium, 2,4-D-diolamine, 2,4-D-isooctyl,2,4-D-isopropyl, 2,4-D-trolamine, (application rate in general: 50-5000g AS/ha, preferably 100-3000 g AS/ha; application ratio(A+B)/C=1:500-5:1, preferably 1:150-2:1);

(C33) bromoxynil (PM, pp. 149-151), for example3,5-dibromo-4-hydroxybenzonitrile, (application rate: 25-1000 g AS/ha,preferably 50-500 g AS/ha; application ratio (A+B)/C=1:100-10:1,preferably 1:25-4:1)

(C34) bentazone (PM, pp. 1064-1066), for example3-isopropyl-2,2-dioxo-1H-2,1,3-benzothiadiazine-4(3H)-one, (applicationrate: 25-1000 g AS/ha, preferably 50-500 g AS/ha; application ratio(A+B)/C=1:100-10:1, preferably 1:25-4:1);

(C35) fluthiacet (PM, pp. 606-608), for example[2-chloro-4-fluoro-5-[5,6,7,8-tetrahydro-3-oxo-1H,3H-1,3,4-thiadiazolo[3,4-a]pyridazine-1-ylideneamino)phenylthio]aceticacid and preferably the methyl ester, (application rate: 100-5000 gAS/ha, preferably 200-3000 g AS/ha; application ratio (A+B)/C=1:500-3:1,preferably 1:150-1:1);

(C36) pyridate (PM, pp.1064-1066), for exampleO-6-chloro-3-phenylpyridazin-4-yl) S-octyl thiocarbonate, (applicationrate:

100-5000 g AS/ha, preferably 200-3000 g AS/ha; application ratio(A+B)/C=1:500-3:1, preferably 1:150-1:1);

(C37) diflufenzopyr (BAS 65 00 H, PM, pp. 81-82), for example2-{1-[4-(3,5-difluorophenyl)semicarbazono]ethyl}nicotinic acid,(application rate in general: 1-500 g AS/ha, preferably 2-300 g AS/ha;application ratio (A+B)/C=1:50-250:1, preferably 1:15-1:1);

(C38) carfentrazone (PM, pp. 191-193), for example ethyl(RS)-2-chloro-3-[2-chloro-5-(4-difluoromethyl-4,5-dihydro-3-methyl-5-oxo-1H-1,2,4-triazol-1-yl)-4-fluorophenyl]propionate, also applied as, interalia, carfentrazone-ethyl (as stated) or else as the acid, (applicationrate: 1-500 g AS/ha, preferably 2-300 g AS/ha; application ratio(A+B)/C=1:50-250:1, preferably 1:15-1:1);

(C39) clopyralid (PM, pp. 260-263), for example3,6-dichloropyridin-2-carboxylic acid, (application rate: 1-300 g AS/ha,preferably 2-200 g AS/ha; application ratio (A+B)/C=1:30-250:1,preferably 1:10-100:1);

(C40) halosulfuron, (PM, pp. 657-659), for example3-chloro-5-(4,6-dimethoxypyrimidin-2-ylcarbamoylsulfamoyl)-1-methylpyrazole-4-carboxylicacid and its esters and salts, preferably the methyl ester, (applicationrate in general: 1-300 g AS/ha, preferably 2-200 g AS/ha; applicationratio (A+B)/C=1:30-250:1, preferably 1:10-100:1);

(C41) thifensulfuron, also including its esters and salts, preferablythe methyl ester (PM, pp.1188-1190), for example3-[[[[(4-methoxy-6-methyl-1,3,5-triazin-2-yl)amino]carbonyl]amino]sulfonyl]-2-thiophenecarboxylicacid or its methyl ester and its salts, (application rate: 1-300 gAS/ha, preferably 2-200 g AS/ha; application ratio (A+B)/C=1:30-250:1,preferably 1:10-100:1);

(C42) prosulfuron, also including its esters and salts, (PM,pp.1041-1043), for example1-(4-methoxy-6-methyl-1,3,5-triazin-2-yl)-3-[2-(3,3,3-trifluoropropyl)phenylsulfonyl]ureaand its salts, (application rate: 1-300 g AS/ha, preferably 2-200 gAS/ha; application ratio (A+B)/C=1:30-250:1, preferably 1: 10-100:1);

(C43) tritosulfuron, also including its esters and salts, (AG Chem, NewCompound Review (publ. Agranova), Vol. 17, 1999, p. 24), for exampleN-[[[4′-methoxy-6-(trifluoromethyl)-1,3,5-triazin-2-yl]amino]carbonyl]-2-trifluoromethylbenzenesulfonamide],(application rate: 0.1-200 g AS/ha, preferably 0.5-100 g AS/ha;application ratio (A+B)/C=1:20-2500:1, preferably 1:5-400:1);

(C44) sulfosulfuron, also including its esters and salts, (PM,pp.1130-1131), for example1-(4,6-dimethoxypyridin-2-yl)-3-(2-ethylsulfonylimidazol[1,2-a]pyridin-3-yl)sulfonylurea,(application rate: 0.1-200 g AS/ha, preferably 0.5-100 g AS/ha;application ratio (A+B)/C=1:20-2500:1, preferably 1:5-400:1);

(C45) ethoxysulfuron, also including its esters and salts, (PM, pp.488-490), for example1-(4,6-dimethoxypyrimidin-2-yl)-3-(2-ethoxyphenoxysulfonyl)urea,(application rate: 5-150 g AS/ha, preferably 10-100 g AS/ha; applicationratio (A+B)/C=1:15-50:1, preferably 1:5-10:1);

(C46) tribenuron, also including its esters and salts, (PM, pp.1230-1232), for example methyl2-[[[[4-methoxy-6-methyl-1,3,5-triazin-2-yl)methylamino]carbonyl]amino]sulfonyl]benzoate,(application rate: 1-100 g AS/ha, preferably 2-80 g AS/ha; applicationratio (A+B)/C=1:10-250:1, preferably 1:5-100:1);

(C47) amidosulfuron, also including its esters and salts, (PM, pp.37-38), for example1-(4,6-dimethoxypyridin-2-yl)-3-mesyl(methyl)sulfamoylurea (applicationrate: 1-100 g AS/ha, preferably 2-80 g AS/ha; application ratio(A+B)/C=1:10-250:1, preferably 1:5-100:1);

(C48) mecoprop, also including mecoprop-p and the esters and salts, (PM,pp. 776-779), for example (RS)-2-(4-chloro-o-tolyloxy)propionic acid,(application rate: 50-5000 g AS/ha, preferably 100-3000 g AS/ha;application ratio (A+B)/C=1:500-5:1, preferably 1:150-2:1);

(C49) dichlorprop, also including dichlorprop-p and the esters andsalts, (PM, pp. 368-372), for example (RS)-2,4-dichlorophenoxy)propionic acid, (application rate: 50-5000 g AS/ha, preferably 100-3000g AS/ha; application ratio (A+B)/C=1:500-5:1, preferably 1:150-2:1);

(C50) fluroxypyr, (PM, pp. 597-600), for example4-amino-3,5-dichloro-6-fluoro-2-pyridyloxyacetic acid, (applicationrate: 5-500 g AS/ha, preferably 10-300 g AS/ha; application ratio (A+B)/C=1:50-50:1, preferably 1:15-20:1);

(CIII) herbicides which act selectively in some mono-/dicotyledonouscrops, predominantly against monocotyledonous harmful plants, selectedfrom the group consisting of

(C51) profluazole (AGROW, No. 338 Oct. 15, 1999, p. 26, PJB PublicationsLtd. 1999, WO 97/15576), for example 1-chloro-N-[2-chloro-4-fluoro-5-[(6S, 7aR)-6-fluorotetrahydro-1,3-dioxo-1H-pyrrolo[1,2-c]imidazol-2(3H)-yl]phenyl]methanesulfonamide,(application rate 5-1000 g AS/ha, preferably 5-800 g AS/ha; quantitativeratio (A+B)/C=1:350-25:1, preferably 1:160-10:1);

(C52) amicarbazone (AGROW, No. 338 October 15, 1999, p. 26, PJBPublications Ltd. 1999, DE 3839206), for example 4-amino-N-(1,1-dimethylethyl)-4,5-dihydro-3-(1-methylethyl)-5-oxo-1H-1,2,4-triazole-1-carboxamide), (application rate 5-1000 g AS/ha,preferably 5-800 g AS/ha; quantitative ratio (A+B)/C=1:350-50:1,preferably 1:160-40:1);

(C53) trifloxysulfuron, also including its esters and salts, for examplethe sodium salt, (AGROW, No. 338 October 15, 1999, p. 26, PJBPublications Ltd. 1999, WO 92/16522), for exampleN-[[(4,6-dimethoxy-2-pyrimidinyl)amino]carbonyl]-3-(2,2,2-trifluoroethoxy)-2-pyridinesulfonamide,(application rate 5-1000 g AS/ha, preferably 5-800 g AS/ha; quantitativeratio (A+B)/C=1:350-25:1, preferably 1:160-10:1);

(CIV) herbicides which are active against monocotyledonous anddicotyledonous harmful plants for use in the nonselective field or inspecifically tolerant crops, selected from the group consisting of

(C54) glufosinate, (PM, pp. 643-645), for exampleD,L-2-amino-4-[hydroxy(methyl)phosphinyl]butanoic acid and its salts andesters (application rate: 10-5000 g AS/ha, preferably 25-4000 g AS/ha;application ratio (A+B)/C=1:500-3:1, preferably 1:200-1:1);

(C55) glufosinate-ammonium, (PM, pp. 643-645), for example amonium4-[hydroxy(methyl)prosphinoyl]-DL-homoalaninate, the monoammonium saltof the acid form, (application rate: 100-5000 g AS/ha, preferably250-4000 g AS/ha; application ratio (A+B)/C=1:500-3:1, preferably1:200-1:1);

(C56) glyphosate, (PM, pp. 646-649), N-(phosphonomethyl)glycine and itssalts and esters, (application rate: 100-5000 g AS/ha, preferably250-4000 g AS/ha; application ratio (A+B)/C=1:500-3:1, preferably1:200-1:1);

for example

(C57) glyphosate-isopropylammonium, (PM, pp. 646-649), for exampleN-(phosphonomethyl)glycine, (application rate: 100-5000 g AS/ha,preferably 250-4000 g AS/ha; application ratio (A+B)/C=1:500-3:1,preferably 1:200-1:1);

(C58) imazapyr, also including its salts and esters, (PM, pp. 697-699),for example 2-(4-isopropyl-4-methyl-5-oxo-2-imidazol in-2-yl)nicotinicacid, (application rate: 1-1000 g AS/ha, preferably 5-500 g AS/ha;application ratio (A+B)/C=1:100-250:1, preferably 1:25-40:1);

(C59) imazethapyr, also including its salts and esters, (PM, pp.701-703),(RS)-5-ethyl-2-(4-isopropyl-4-methyl-5-oxo-2-imidazolin-2-yl)nicotinicacid, (application rate: 1-1000 g AS/ha, preferably 5-500 g AS/ha;application ratio (A+B)/C=1:100-250:1, preferably 1:25-40:1);

(C60) imazamethabenz, also including its salts and esters, (PM, pp.694-696), for example imazamethabenz-methyl, for example methyl(±)-6-(4-isopropyl-4-methyl-5-oxo-2-imid azolin-2-yl)-m-toluate,(application rate: 1-1000 g AS/ha, preferably 5-500 g AS/ha; applicationratio -(A+B)/ C=1:100-250:1, preferably 1:25-40:1);

(C61) imazamox, also including its salts and esters, (PM, pp. 696-697),for example(RS)-2-(4-isopropyl-4-methyl-5-oxo-2-imidazolin-2-yl)-5-methoxymethylnicotinicacid, (application rate: 1-1000 g AS/ha, preferably 5-500 g AS/ha;application ratio (A+B)/C=1:100-250:1, preferably 1:25-40:1);

(C62) imazaquin, also including its salts and esters, for example theammonium salt (PM, pp. 699-701), for example(RS)-2-(4-isopropyl-4-methyl-5-oxo-2-imidazolin-2-yl)qu inolin-3-carboxylic acid, (application rate: 1-1000 g AS/ha, preferably5-500 g AS/ha; application ratio (A+B)/C=1:100-250:1, preferably1:25-40:1) and

(C63) imazapic (AC 263,222), also including its salts and esters, forexample the ammonium salt, (PM, pp. 5 and 6, referred to as AC 263,222),for example(RS)-2-(4,5-dihydro-4-isopropyl-4-methyl-5-oxoimidazol-2-yl)-5-methylnicotinicacid, (application rate: 1-1000 g AS/ha, preferably 5-500 g AS/ha;application ratio (A+B)/C=1:100-250:1, preferably 1:25-40:1).

If the abbreviation of the “common name” is used within the presentdescription, it comprises all conventional derivatives, such as theesters and salts, and isomers, in particular the optical isomers, inparticular the commercially available form or forms. If the “commonname” refers to an ester or salt, this also includes all of the otherusual derivatives, such as other esters and salts, the free acids,neutral compounds and isomers, in particular optical isomers, inparticular the commercially available form or forms. The chemicalcompound names stated refer at least to one of the compounds encompassedby the “common name”, frequently to a preferred compound. In the case ofsulfonamides, such as sulfonylureas, salts also include those which areformed by exchanging a hydrogen atom on the sulfonamide group by acation.

The herbicide combinations according to the invention have aherbicidally active content of components (A), (B) and (C) and maycomprise further components, for example other types of agrochemicalsand/or formulation auxiliaries and/or additives conventionally used incrop protection, or they may be employed together with these. Preferredherbicide combinations are those with a synergistically active contentof components (A), (B) and (C).

The herbicide combinations according to the invention preferably havesynergistic effects. The synergistic effects are observed when theherbicides (A), (B) and (C) are applied together, but can frequentlyalso be found when applied as a split application over time. Anotherpossibility is to apply the individual herbicides or the herbicidecombinations in several portions (sequential application), for examplepre-emergence applications, followed by post-emergence applications orearly post-emergence applications, followed by applications at medium orlate post-emergence. Preferred is the simultaneous or nearlysimultaneous application of the active ingredients of the herbicidecombination according to the invention.

The synergistic effects allow reduction of the application rates of theindividual active ingredients, a more potent action with the sameapplication rate, the control of species to which no control hasextended as yet (zero action), an extended application period and/or areduced number of individual applications required and—as a result forthe user—more advantageous weed control systems from the economical andecological angle.

The herbicidal components of group (C1) act against monocotyledonous anddicotyledonous harmful plants. The herbicidal components of group (CII)act predominantly against dicotyledonous harmful plants, but can also beactive against monocotyledonous harmful plants in some cases. Theherbicidal components of group (CIII) act predominantly againstmonocotyledonous harmful plants, but can also be active againstdicotyledonous harmful plants in some cases. The herbicidal componentsof group (CIV) are active against mono- and dicotyledonous harmfulplants when employed in the nonselective field or in specificallytolerant crops.

The abovementioned formula (I) encompasses all stereoisomers and theirmixtures, in particular also racemic mixtures and—if enantiomers arepossible—the particular enantiomer which has a biological action.Compounds of the formula (I) and their salts and also their preparationare described, for example, in WO 95/29899. Examples of activeingredients of the formula (I) and their salts areN-[N-(4,6-dimethoxypyrimidin-2-yl)-aminocarbonyl]-2-(dimethylaminocarbonyl)-5-(formylamino)benzenesulfonamide(foramsulfuron, A1) and its salts such as the sodium salt(foramsulfuron-sodium, A2) (see, for example, AGROW No. 338, Oct. 15,1999, page 26, PJB Publications Ltd. 1999).

The above formula (II) encompasses all stereoisomers and their mixtures,in particular also racemic mixtures, and—in as far as enantiomers arepossible, all of the biologically active enantiomers. Compounds of theformula (II), their salts and their preparation are described, forexample, in WO 92/13845. Examples of active compounds of the formula(II) and their salts are3-(4-methoxy-6-methyl-1,3,5-triazin-2-yl)-1-(2-methoxycarbonyl-5-iodophenylsulfonyl)urea(iodosulfuron-methyl, B1) and its salts, such as the sodium salt(iodosulfuron-methyl-sodium, B2) (see, for example, WO 92/13845 and PM,pp. 547-548).

The abovementioned herbicides of the formulae (I) and (II) and theirsalts may inhibit the enzyme acetolactate synthase (ALS) and thusprotein synthesis in plants. The application rate of the herbicides ofthe formulae (I) and (II) can vary within a wide range, for examplebetween 0.001 and 0.5 kg of AS/ha. The abbreviation AS/ha used in thisdescription means active substance per hectare, based on 100% activeingredient. In the case of applications at application rates of 0.01 to0.1 kg of AS/ha of the herbicides of the formulae (I) and (II),preferably of the formulae (A1), (A2), (B1) or (B2), a relatively broadspectrum of annual and perennial broad-leaved weeds, grass weeds andcyperacea is controlled pre- and post-emergence. The application ratesin the case of the combinations according to the invention are, as arule, lower, e.g. in the range from 0.5 to 120 g of AS/ha, preferably 2to 80 g of AS/ha.

As a rule, the active ingredients can be formulated as water-solublewettable powders (WP), water-dispersible granules (WDG),water-emulsifiable granules (WEG), suspoemulsion (SE) or oil suspensionconcentrate (SC).

The quantitative ratios (A+B)/C which are generally used are statedhereinabove and identify the weight ratio of the two components (A+B)and C to each other. The weight ratio of the components A and B to eachother is generally 1:50-1200:1, preferably 1:10-500:1.

For use of the active ingredients of the formulae (I) and (II) or theirsalts in plant crops, it is expedient, depending on the plant crop, toapply a safener from certain application rates upward in order to reduceor to avoid damage to the crop plants. Examples of suitable safeners arethose which have a safener action in combination with sulfonylureaherbicides, preferably phenylsulfonylureas. Suitable safeners aredisclosed in WO-A-96/14747 and the literature cited therein.

The following groups of compounds are examples of suitable safeners forthe abovementioned herbicidal active ingredients (A) and (B):

a) Compounds of the dichlorophenylpyrazoline-3-carboxylic acid (S1type), preferably compounds such as ethyl1-(2,4-dichlorophenyl)-5-(ethoxycarbonyl)-5-methyl-2-pyrazoline-3-carboxylate(S1-1, mefenpyr-diethyl, PM, pp. 781-782), and related compounds as theyare described in WO 91/07874.

b) Dichlorophenylpyrazolecarboxylic acid derivatives, preferablycompounds such as ethyl1-(2,4-dichlorophenyl)-5-methylpyrazole-3-carboxylate (S1-2), ethyl1-(2,4-d ichlorophenyl)-5-isopropylpyrazole-3-carboxylate (S1-3), ethyl1-(2,4-dichlorophenyl)-5-(1,1-dimethyl-ethyl)pyrazole-3- carboxylate(S1-4), ethyl 1-(2,4-dichlorophenyl)-5-phenylpyrazole-3- carboxylate(S1-5) and related compounds as are described in EP-A-333 131 andEP-A-269 806.

c) Compounds of the triazolecarboxylic acid (S1) type, preferablycompounds such as fenchlorazole, i.e. ethyl

1-(2,4-dichlorophenyl)-5-trichloromethyl-(1H)-1,2,4-triazole-3-carboxylate(S1-6) and related compounds (see EP-A-174 562 and EP-A-346 620).

d) Compounds of the 5-benzyl- or 5-phenyl-2-isoxazoline-3-carboxylicacid type or of the 5,5-diphenyl-2-isoxazoline-3-carboxylic acid type,preferably compounds such as ethyl 5-(2,4-dichlorobenzyl)-2-isoxazoline-3-carboxylate (S1-7) or ethyl5-phenyl-2-isoxazoline-3-carboxylate (S1-8) and related compounds as aredescribed in WO 91/08202, or of ethyl5,5-diphenyl-2-isoxazolinecarboxylate (S1-9, isoxadifen-ethyl) orn-propyl 5,5-diphenyl-2-isoxazolinecarboxylate (S1-0) or ethyl5-(4-!fluorophenyl)-5-phenyl-2-isoxazoline-3-carboxylate (S1-11), as aredescribed in Patent Application (WO-A-95/07897).

e) Compounds of the 8-quinoline oxyacetic acid (S2) type, preferably1-methylhex-1-yl (5-chloro-8-quinolinoxy)acetate (S2-1,cloquintocet-mexyl, e.g. PM, pp. 263-264),

(1,3-dimethyl but-1-yl) (5-chloro-8-quinolinoxy)acetate (S2-2),4-allyloxybutyl (5-chloro-8-quinolinoxy)acetate (S2-3),1-allyloxyprop-2-yl (5-chloro-8-quinolinoxy)acetate (S2-4), ethyl(5-chloro-8-quinolinoxy)acetate (S2-5), methyl(5-chloro-8-quinolinoxy)acetate (S2-6), allyl(5-chloro-8-quinolinoxy)acetate (S2-7),2-(2-propylideneiminooxy)-1-ethyl (5-chloro-8-quinolinoxy)acetate(S2-8), 2-oxoprop-1-yl (5-chloro-8-quinolinoxy)acetate (S2-9) andrelated compounds as are described in EP-A-8 750, EP-A-94 349 andEP-A-191 736 or EP-A-0 492 366.

f) Compounds of the (5-chloro-8-quinolinoxy)malonic acid type,preferably compounds such as diethyl (5-chloro-8-quinolinoxy)malonate,diallyl (5-chloro-8-qu inoli noxy)malonate, methyl ethyl(5-chloro-8-quinolinoxy)-malonate and related compounds as are describedin EP-A-0 582 198.

g) Active ingredients of the phenoxyacetic acids, phenoxypropionic acidsor aromatic carboxylic acids type, such as, for example,2,4-dichlorophenoxyacetic acid (and esters) (2,4-D),4-chloro-2-methylphenoxypropionic esters (mecoprop), MCPA or3,6-dichloro-2-methoxybenzoic acid (and esters) (dicamba).

In many cases, the abovementioned safeners are also suitable for activeingredients of group (B). In addition, the following safeners aresuitable for the herbicide combinations according to the invention:

h) active ingredients of the pyrimidine type, such as “fenclorim” (PM,pp. 512-511) (=4,6-dichloro-2-phenylpyrimidine),

i) active ingredients of the dichloroacetamide type, whichare.frequently used as pre-emergence safeners (soil-acting safeners)such as, for example, “dichloromid” (PM, pp. 363-364)(=N,N-diallyl-2,2-dichloroacetamide), “AR-29148”(=3-dichloroacetyl-2,2,5-trimethyl-1,3-oxazolidone by Stauffer),“benoxacor” (PM, pp. 102-103)(=4-dichloroacetyl-3,4-dihydro-3-methyl-2H-1,4-benzoxazine),

“APPG-1292” (=N-allyl-N[(1,3-dioxolan-2-yl)-methyl]dichloroacetamide byPPG Industries),

“ADK-24” (=N-allyl-N-[(allylaminocarbonyl)-methyl]-d ich loroacetamideby Sagro-Chem),

“AAD-67” or “AMON 4660)” (=3-dichloroacetyl-1-oxa-3-aza-spiro[4,5]decaneby Nitrokemia or Monsanto), “diclonon” or “ABAS145138” or “ALAB145138”(=(=3-dichloroacetyl-2,5,5-trimethyl-1,3-diazabicyclo[4.3.0]nonane byBASF) and “furilazol” or “AMON 13900” (see PM, 637-638)(=(RS)-3-dichloroacetyl-5-(2-furyl)-2,2-dimethyloxazolidone)

j) active ingredients of the dichloroacetones type, such as, forexample, “AMG 191” (CAS Reg. No. 96420-72-3)(=2-dichloromethyl-2-methyl-1,3-dioxolane by Nitrokemia),

k) active ingredients of the oxyimino compounds type which are known asseed-dressing materials such as, for example,

“oxabetrinil” (PM, pp. 902-903)(=(Z)-1,3-dioxolan-2-ylmethoxyimino(phenyl)acetonitrile), which is knownas safener in seed dressing to prevent metolachlor damage,

“fluxofenim” (PM, pp. 613-614)(=1-(4-chlorophenyl)-2,2,2-trifluoro-1-ethanoneO-(1,3-dioxolan-2-ylmethyl)-oxime, which is known as safener in seeddressing to prevent metolachlor damage, and

“cyometrinil” or “A-CGA-43089” (PM, p.1304)(=(Z)-cyanomethoxyimino(phenyl)acetonitrile), which is known as safenerin seed dressing to prevent metolachlor damage,

l) active ingredients of the thiazolecarboxylic esters type, which areknown as seed-dressing materials, such as, for example,

“flurazol” (PM, pp. 590-591) (=benzyl2-chloro-4-trifluoromethyl-1,3-thiazole-5-carboxylate), which is knownas safener in seed dressing to prevent alachlor and metolachlor damage,

m) active ingredients of the naphthalenedicarboxylic acids type whichare known as seed-dressing agents, such as, for example,

“naphthalic anhydride” (PM, p.1342) (=1,8-naphthalenedicarboxylicanhydride), which is known as safener for maize in seed dressing toprevent thiocarbamate herbicide damage,

n) active ingredients of the chromaneacetic acids type, such as, forexample, “ACL 304415” (CAS Reg. No. 31541-57-8)(=2-84-carboxychroman-4-yl)acetic acid by American Cyanamid),

o) active ingredients which, in addition to a herbicidal action againstharmful plants, also have a safener action on crop plants, such as, forexample, “dimepiperate” or AMY-93“(PM, pp.404-405)(=S-1-methyl-1-phenylethyl piperidine-1-carbothioate),

“daimuron” or “ASK 23” (PM, p.330)(=1-(l-methyl-l-phenylethyl)-3-p-tolylurea),

“cumyluron”=“AJC-940”(=3-(2-chlorophenylmethyl)-1-(1-methyl-1-phenyl-ethyl)urea, seeJP-A-60087254),

“methoxyphenon” or “ANK 049” (=3,3′-dimethyl-4-methoxy-benzophenone),

“CSB” (=1-bromo-4-(chloromethylsulfonyl)benzene) (CAS Reg. No.54091-06-4 by Kumiai).

The herbicides (A) and (B) are suitable for controlling harmful plantsin crops of plants, for example in economically important crops such ascereals (for example wheat, barley, rye, oats, rice, maize, sorghum andmillet, sugar beet, sugar cane, oilseed rape, cotton and soya, inparticular in maize, if appropriate in the presence of safeners (forexample, the combination (A1)+(S1-9) is commercially available under thename Optiono and the combination (A1)+(B2)+(S1-9) under the nameMaisTero). The above crops are also preferred for the combinations(A)+(B)+(C).

Also encompassed by the invention are those herbicide combinations whichadditionally contain one or more further agrochemical active compoundswith a different structure, such as herbicides, insecticides, fungicidesor safeners, besides the components (A), (B) and (C). If suchcombinations also contain the combinations (A)+(B)+(C) according to theinvention, the preferred conditions mentioned hereinbelow, in particularfor combinations (A)+(B)+(C) according to the invention, also mainlyapply to such combinations with regard to the combination (A)+(B)+(C) inquestion.

Of particular interest is the application of herbicidal compositionswhich comprise the following compounds (A)+(B)+(C):

(A1)+(B1)+(C1), (A1)+(B1)+(C2), (A1)+(B1)+(C3), (A1)+(B1)+(C4),(A1)+(B1)+(C5), (A1)+(B1)+(C6), (A1)+(B1)+(C7), (A1)+(B1)+(C8),(A1)+(B1)+(C9), (A1)+(B1)+(C10), (A1)+(B1)+(C11), (A1)+(B1)+(C12),(A1)+(B1)+(C13), (A1)+(B1)+(C14), (A1)+(B1)+(C15), (A1)+(B1)+(C16),(A1)+(B1)+(C17), (A1)+(B1)+(C18), (A1)+(B1)+(C19), (A1)+(B1)+(C20),(A1)+(B1)+(C21), (A1)+(B1)+(C22), (A1)+(B1)+(C23), (A1)+(B1)+(C24),(A1)+(B1)+(C25), (A1)+(B1)+(C26), (A1)+(B1)+(C27), (A1)+(B1)+(C28),(A1)+(B1)+(C29), (A1)+(B1)+(C30), (A1)+(B1)+(C31), (A1)+(B1)+(C32),(A1)+(B1)+(C33), (A1)+(B1)+(C34),(A1)+(B1)+(C35),(A1)+(B1)+(C36),(A1)+(B1)+(C37), (A1)+(B1)+(C38), (A1)+(B1)+(C39), (A1)+(B1)+(C40),(A1)+(B1)+(C41),(A1)+(B1)+(C42),(A1)+(B1)+(C43),(A1)+(B1)+(C44),(A1)+(B1)+(C45),(A1)+(B1)+(C46),(A1)+(B1)+(C47),(A1)+(B1)+(C48),(A1)+(B1)+(C49),(A1)+(B1)+(C50), (A1)+(B1)+(C51), (A1)+(B1)+(052), (A1)+(B1)+(C53),(A1)+(B1)+(C54), (A1)+(B1)+(C55), (A1)+(B1)+(C56), (A1)+(B1)+(C57),(A1)+(B1)+(C58), (A1)+(B1)+(C59), (A1),+(B1)+(C60), (A1)+(B1)+(C61),(A1)+(B1)+(C62), (A1)+(B1)+(C63);

(A1)+(B2)+(C1), (A1)+(B2)+(C), (A1)+(B2)+(C3), (A1)+(B2)+(C4),(A1)+(B2)+(C5), (A1)+(B2)+(C6), (A1)+(B2)+(C7), (A1)+(B2)+(C8),(A1)+(B2)+(C9), (A1)+(B2)+(C10), (A1)+(B2)+(C11), (A1)+(B2)+(C12),(A1)+(B2)+(C13), (A1)+(B2)+(C14), (A1)+(B2)+(C15), (A1)+(B2)+(C16),(A1)+(B2)+(C17), (A1)+(B2)+(C18), (A1)+(B2)+(C19), (A1)+(B2)+(C20),(A1)+(B2)+(C21), (A1)+(B2)+(C22), (A1)+(B2)+(C23), (A1)+(B2)+(C24),(A1)+(B2)+(C25), (A1)+(B2)+(C26), (A1)+(B2)+(C27), (A1)+(B2)+(C28),(A1)+(B2)+(C29), (A1)+(B2)+(C30), (A1)+(B2)+(C31), (A1)+(B2)+(C32),(A1)+(B2)+(C33), (A1)+(B2)+(C34), (A1)+(B2)+(C35), (A1)+(B2)+(C36),(A1)+(B2)+(C37), (A1)+(B2)+(C38), (A1)+(B2)+(C39), (A1)+(B2)+(C40),(A1)+(B2)+(C41), (A1)+(B2)+(C42), (A1)+(B2)+(C43), (A1)+(B2)+(C44),(A1)+(B2)+(C45), (A1)+(B2)+(C46), (A1)+(B2)+(C47), (A1)+(B2)+(C48),(A1)+(B2)+(C49), (A1)+(B2)+(C50), (A1)+(B2)+(C51), (A1)+(B2)+(C52),(A1)+(B2)+(C53), (A1)+(B2)+(C54), (A1)+(B2)+(C55), (A1)+(B2)+(C56),(A1)+(B2)+(C57), (A1)+(B2)+(C58), (A1)+(B2)+(C59), (A1)+(B2)+(C60),(A1)+(B2)+(C61), (A1)+(B2)+(C62), (A1)+(B2)+(C63);

(A2)+(B1)+(C1), (A2)+(B1)+(C2), (A2)+(B1)+(C3), (A2)+(B1)+(C4),(A2)+(B1)+(C5), (A2)+(B1)+(C6), (A2)+(B1)+(C7), (A2)+(B1)+(C8),(A2)+(B1)+(C9),(A2)+(B1)+(C10),(A2)+(B1)+(C11),(A2)+(B1)+(C12),(A2)+(B1)+(C13),(A2)+(B1)+(C14), (A2)+(B1)+(C15), (A2)+(B1)+(C16), (A2)+(B1)+(C17),(A2)+(B1)+(C18), (A2)+(B1)+(C19), (A2)+(B1)+(C20), (A2)+(B1)+(C21),(A2)+(B1)+(C22), (A2)+(B1)+(C23), (A2)+(B1)+(C24), (A2)+(B1)+(C25),(A2)+(B1)+(C26), (A2)+(B1)+(C27), (A2)+(B1)+(C28), (A2)+(B1)+(C29),(A2)+(B1)+(C30), (A2)+(B1)+(C31), (A2)+(B1)+(C32), (A2)+(B1)+(C33),(A2)+(B1)+(C34), (A2)+(B1)+(C35), (A2)+(B1)+(C36), (A2)+(B1)+(C37),(A2)+(B1)+(C38), (A2)+(B1)+(C39), (A2)+(B1)+(C40), (A2)+(B1)+(C41),(A2)+(B1)+(C42), (A2)+(B1)+(C43), (A2)+(B1)+(C44), (A2)+(B1)+(C45),(A2)+(B1)+(C46), (A2)+(B1)+(C47), (A2)+(B1)+(C48), (A2)+(B1)+(C49),(A2)+(B1)+(C50), (A2)+(B1)+(C51), (A2)+(B1)+(C52), (A2)+(B1)+(C53),(A2)+(B1)+(C54), (A2)+(B1)+(C55), (A2)+(B1)+(C56), (A2)+(B1)+(C57),(A2)+(B1)+(C58), (A2)+(B1)+(C59), (A2)+(B1)+(C60), (A2)+(B1)+(C61),(A2)+(B1)+(C62), (A2)+(B1)+(C63);

(A2)+(B2)+(C1), (A2)+(B2)+(C2), (A2)+(B2)+(C3), (A2)+(B2)+(C4),(A2)+(B2)+(C5), (A2)+(B2)+(C6), (A2)+(B2)+(C7), (A2)+(B2)+(C8),(A2)+(B2)+(C9), (A2)+(B2)+(C10), (A2)+(B2)+(C11), (A2)+(B2)+(C12),(A2)+(B2)+(C13), (A2)+(B2)+(C14), (A2)+(B2)+(C15), (A2)+(B2)+(C16),(A2)+(B2)+(C17), (A2)+(B2)+(C18), (A2)+(B2)+(C19), (A2)+(B2)+(C20),(A2)+(B2)+(C21), (A2)+(B2)+(C22), (A2)+(B2)+(C23), (A2)+(B2)+(C24),(A2)+(B2)+(C25), (A2)+(B2)+(C26), (A2)+(B2)+(C27), (A2)+(B2)+(C28),(A2)+(B2)+(C29), (A2)+(B2)+(C30), (A2)+(B2)+(C31), (A2)+(B2)+(C32),(A2)+(B2)+(C33), (A2)+(B2)+(C34), (A2)+(B2)+(C35), (A2)+(B2)+(C36),(A2)+(B2)+(C37), (A2)+(B2)+(C38), (A2)+(B2)+(C39), (A2)+(B2)+(C40),(A2)+(B2)+(C41), (A2)+(B2)+(C42), (A2)+(B2)+(C43), (A2)+(B2)+(C44),(A2)+(B2)+(C45), (A2)+(B2)+(C46), (A2)+(B2)+(C47), (A2)+(B2)+(C48),(A2)+(B2)+(C49), (A2)+(B2)+(C50), (A2)+(B2)+(C51), (A2)+(B2)+(052),(A2)+(B2)+(C53), (A2)+(B2)+(C54), (A2)+(B2)+(C55), (A2)+(B2)+(C56),(A2)+(B2)+(C57), (A2)+(B2)+(C58), (A2)+(B2)+(C59), (A2)+(B2)+(C60),(A2)+(B2)+(C61), (A2)+(B2)+(C62), (A2)+(B2)+(C63);

(A1)+(A2)+(B1)+(B2)+(C1),(A1)+(A2)+(B1)+(B2)+(C2),(A1)+(A2)+(B1)+(B2)+(C3),(A1)+(A2)+(B1)+(B2)+(C4), (A1)+(A2)+(B1)+(B2)+(C5),(A1)+(A2)+(B1)+(B2)+(C6), (A1)+(A2)+(B1)+(B2)+(C7),(A1)+(A2)+(B1)+(B2)+(C8), (A1)+(A2)+(B1)+(B2)+(C9),(A1)+(A2)+(B1)+(B2)+(C10), (A1)+(A2)+(B1)+(B2)+(C11),(A1)+(A2)+(B1)+(B2)+(C12), (A1)+(A2)+(B1)+(B2)+(C13),(A1)+(A2)+(B1)+(B2)+(C14), (A1)+(A2)+(B1)+(B2)+(C15),(A1)+(A2)+(B1)+(B2)+(C16), (A1)+(A2)+(B1)+(B2)+(C17),(A1)+(A2)+(B1)+(B2)+(C18),(A1)+(A2)+(B1)+(B2)+(C19),(A1)+(A2)+(B1)+(B2)+(C20),(A1)+(A2)+(B1)+(B2)+(C21), (A1)+(A2)+(B1)+(B2)+(C22),(A1)+(A2)+(B1)+(B2)+(C23), (A1)+(A2)+(B1)+(B2)+(C24),(A1)+(A2)+(B81)+(B2)+(C25), (A1)+(A2)+(B1)+(B2)+(C26),(A1)+(A2)+(B1)+(B2)+(C27), (A1)+(A2)+(B1)+(B2)+(C28),(A1)+(A2)+(B1)+(B2)+(C29),(A1)+(A2)+(B1)+(B2)+(C30),(A1)+(A2)+(B1)+(B2)+(C31),(A1)+(A2)+(B1)+(B2)+(C32),(A1)+(A2)+(B1)+(B2)+(C33),(A1)+(A2)+(B1)+(B2)+(C34),(A1)+(A2)+(B1)+(B2)+(C35), (A1)+(A2)+(B1)+(B2)+(C36),(A1)+(A2)+(B1)+(B2)+(C37), (A1)+(A2)+(B1)+(B2)+(C38),(A1)+(A2)+(B1)+(B2)+(C39), (A1)+(A2)+(B1)+(B2)+(C40),(A1)+(A2)+(B1)+(B2)+(C41),(A1)+(A2)+(B1)+(B2)+(C42),(A1)+(A2)+(B1)+(B2)+(C43),(A1)+(A2)+(B1)+(B2)+(C44),(A1)+(A2)+(B1)+(B2)+(C45), (A1)+(A2)+(B1)+(B2)+(C46),(A1)+(A2)+(B1)+(B2)+(C47), (A1)+(A2)+(B1)+(B2)+(C48),(A1)+(A2)+(B1)+(B2)+(C49), (A1)+(A2)+(B1)+(B2)+(C50),(A1)+(A2)+(B1)+(B2)+(C51), (A1)+(A2)+(B1)+(B2)+(C52),(A1)+(A2)+(B1)+(B2)+(C53),(A1)+(A2)+(B1)+(B2)+(C54),(A1)+(A2)+(B1)+(B2)+(C55),(A1)+(A2)+(B1)+(B2)+(C56),(A1)+(A2)+(B1)+(B2)+(C57), (A1)+(A2)+(B1)+(B2)+(c58),(A1)+(A2)+(B1)+(B2)+(C59), (A1)+(A2)+(B1)+(B2)+(C60),(A1)+(A2)+(B1)+(B2)+(C61), (A1)+(A2)+(B1)+(B2)-+(C62),(A1)+(A2)+(B1)+(B2)+(C63).

In addition, each of the abovementioned herbicide combinations mayadditionally also contain one or more safeners, in particular a safenersuch as mefenpyr-diethyl (S1-1), isoxadifen-ethyl (S1-9) andcloquintocet-methyl (S2-1). In this context, the abovementioned rangesof the application rates, and application ratios, are preferred in eachcase. Examples are the herbicide combinations mentioned hereinbelow.

(A1)+(B1)+(C1)+(S1-1), (A1)+(B1)+(C2)+(S1-l), (A1)+(B1)+(C3)+(S1-1),(A1)+(B1)+(C4)+(S1-1), (A1)+(B1)+(C5)+(S1-1), (A1)+(B1)+(C6)+(S1-1),(A1)+(B1)+(C7)+(S1-1), (A1)+(B1)+(C8)+(S1-1), (A1)+(B1)+(C9)+(S1-1),(A1)+(B1)+(C10)+(S1-1), (A1)+(B1)+(C1)+(S1-1), (A1)+(B1)+(C12)+(S1-1),(A1)+(B1)+(C13)+(S1-1), (A1)+(B1)+(Ci4)+(S1-1); (A1)+(B1)+(C15)+(S1-1),(A1)+(B1)+(Ci6)+(S1-1), (A1)+(B1)+(C17)+(S1-1), (A1)+(B1)+(C18)+(S1-1),(A1)+(B1)+(C19)+(S1-1), (A1)+(B1)+(C20)+(S1-1),(A1)+(B1)+(C21)+(S1-1),(A1)+(B1)+(C22)+(S1-1),(A1)+(B1)+(C23)+(S1-1),(A1)+(B1)+(C24)+(S1-1), (A1)+(B1)+(C25)+(S1-1), (A1)+(B1)+(C26)+(S1-1),(A1)+(B1)+(C27)+(S1-1), (A1)+(B1)+(C28)+(S1-1), (A1)+(B1)+(C29)+(S1-1),(A1)+(B1)+(C30)+(S1-l), (A1)+(B1)+(C31)+(S1-1), (A1)+(B1)+(C32)+(S1-1),(A1)+(B1)+(C33)+(S1-1), (A1)+(B1)+(C34)+(S1-1), (A1)+(B1)+(C35)+(S1-1),(A1)+(B1)+(C36)+(S1-1), (A1)+(B1)+(C37)+(S1-1), (A1)+(B1)+(C38)+(S1-1),(A1)+(B1)+(C39)+(S1-1), (A1)+(B1)+(C40)+(S1-1), (A1)+(B1)+(C41)+(S1-1),(A1)+(B1)+(C42)+(S1-1), (A1)+(B1)+(C43)+(S1-1), (A1)+(B1)+(C44)+(S1-1),(A1)+(B1)+(C45)+(S1-1),(A1)+(B1)+(C46)+(S1-1),(A1)+(B1)+(C47)+(S1-1),(A1)+(B1)+(C48)+(S1-1),(A1)+(B1)+(C49)+(S1-1),(A1)+(B1)+(C50)+(S1-1),(A1)+(B1)+(C51)+(S1-1),(A1)+(B1)+(C52)+(S1-1), (A1)+(B1)+(C53)+(S1-1), (A1)+(B1)+(C54)+(S1-1),(A1)+(B1)+(C55)+(S1-1), (A1)+(B1)+(C56)+(S1-1), (A1)+(B1)+(C57)+(S1-1),(A1)+(B1)+(C58)+(S1-1), (A1)+(B1)+(C59)+(S1-1), (A1)+(B1)+(C60)+(S1-1),(A1)+(B1)+(C61)+(S1-1), (A1)+(B1)+(C62)+(S1-1),(A1)+(B1)+(C63)+(S1-1);

(A1)+(B2)+(C1)+(S1-1),(A1)+(B2)+(C)+(S1-1),(A1)+(B2)+(C3)+(S1-1),(A1)+(B2)+(C4)+(S1-1), (A1)+(B2)+(C5)+(S1-1), (A1)+(B2)+(C6)+(S1-1),(A1)+(B2)+(C7)+(S1-1), (A1)+(B2)+(C8)+(S1-1), (A1)+(B2)+(C9)+(S1-1),(A1)+(B2)+(C10)+(S1-1),(A1)+(B2)+(C1)+(S1-1),(A1)+(B2)+(C12)+(S1-1),(A1)+(B2)+(C13)+(S1-1), (A1)+(B2)+(C14)+(S1-1), (A1)+(B2)+(C15)+(S1-1),(A1)+(B2)+(C16)+(S1-1), (A1)+(B2)+(C17)+(S1-1), (A1)+(B2)+(C08)+(S1-1),(A1)+(B2)+(Ci9)+(S1-1), (A1)+(B2)+(C20)+(S1-1), (A1)+(B2)+(C21)+(S1-1),(A1)+(B2)+(C22)+(S1-1), (A1)+(B2)+(C23)+(S1-1), (A1)+(B2)+(C24)+(S1-1),(A1)+(B2)+(C25)+(S1-1), (A1)+(B2)+(C26)+(S1-1), (A1)+(B2)+(C27)+(S1-1),(A1)+(B2)+(C28)+(S1-1), (A1)+(B2)+(C29)+(S1-1)), (A1)+(B2)+(C30)+(S1-1),(A1)+(B2)+(C31)+(S1-1), (A1)+(B2)+(C32)+(S1-1), (A1)+(B2)+(C33)+(S1-1),(A1)+(B2)+(C34)+(S1-1), (A1)+(B2)+(C35)+(S1-1), (A1)+(B2)+(C36)+(S1-1),(A1)+(B2)+(C37)+(S1-1), (A1)+(B2)+(C38)+(S1-1), (A1)+(B2)+(C39)+(S1-1),(A1)+(B2)+(C40)+(S1-1), (A1)+(B2)+(C41)+(S1-1), (A1)+(B2)+(C42)+(S1-1),(A1)+(B2)+(C43)+(S1-1), (A1)+(B2)+(C44)+(S1-1), (A1)+(B2)+(C45)+(S1-1),(A1)+(B2)+(C46)+(S1-1), (A1)+(B2)+(C47)+(S1-1)), (A1)+(B2)+(C48)+(S1-1),(A1)+(B2)+(C49)+(S1-1), (A1)+(B2)+(C50)+(S1-1), (A1)+(B2)+(C51)+(S1-1),(A1)+(B2)+(C52)+(S1-1), (A1)+(B2)+(C53)+(S1-1), (A1)+(B2)+(C54)+(S1-1),(A1)+(B2)+(C55)+(S1-1),(A1)+(B2)+(C56)+(S1-1),(A1)+(B2)+(C57)+(S1-1),(A1)+(B2)+(C58)+(S1-1),(A1)+(B2)+(C59)+(S1-1),(A1)+(B2)+(C60)+(S1-1), (A1)+(B2)+(C61)+(S1-1), (A1)+(B2)+(C62)+(S1-1),(A1)+(B2)+(C63)+(S1-1);

(A2)+(B1)+(C1)+(S1-1), (A2)+(B1)+(C2)+(S1-1), (A2)+(B1)+(C3)+(S1-1),(A2)+(B1)+(C4)+(S1-1),(A2)+(B1)+(C5)+(S1-1),(A2)+(B1)+(C6)+(S1-1),(A2)+(B1)+(C7)+(S1-1), (A2)+(B1)+(C8)+(S1-1), (A2)+(B1)+(C9)+(S1-1),(A2)+(B1)+(C10)+(S1-1), (A2)+(B1)+(C11)+(S1-1), (A2)+(B1)+(C12)+(S1-1),(A2)+(B1)+(C13)+(S1-1), (A2)+(B1)+(C14)+(S1-1), (A2)+(B1)+(C15)+(S1-1),(A2)+(B1)+(C16)+(S1-1), (A2)+(B1)+(C17)+(S1-1),(A2)+(B1)+(C18)+(S1-1),(A2)+(B1)+(C19)+(S1-1),(A2)+(B1)+(C20)+(S1-1)),(A2)+(B1)+(C21)+(S1-1), (A2)+(B1)+(C22)+(S1-1)), (A2)+(B1)+(C23)+(S1-1),(A2)+(B1)+(C24)+(S1-1), (A2)+(B1)+(C25)+(S1-1), (A2)+(B1)+(C26)+(S1-1),(A2)+(B1)+(C27)+(S1-1), (A2)+(B1)+(C28)+(S1-1), (A2)+(B1)+(C29)+(S1-1),(A2)+(B1)+(C30)+(S1-1), (A2)+(B1)+(C31) # (S1-1),(A2)+(B1)+(C32)+(S1-1),(A2)+(B1)+(C33)+(S1-1),(A2)+(B1)+(C34)+(S1-1),(A2)+(B1)+(C35)+(S1-1), (A2)+(B1)+(C36)+(S1-1), (A2)+(B1)+(C37)+(S1-1),(A2)+(B1)+(C38)+(S1-1), (A2)+(B1)+(C39)+(S1-1), (A2)+(B1)+(C40)+(S1-1),(A2)+(B1)+(C41)+(S1-1), (A2)+(B1)+(C42)+(S1-1), (A2)+(B1)+(C43)+(S1-1),(A2)+(B1)+(C44)+(S1-1),(A2)+(B1)+(C45)+(S1-1),(A2)+(B1)+(C46)+(S1-1),(A2)+(B1)+(C47)+(S1-1),(A2)+(B1)+(C48)+(S1-1),(A2)+(B1)+(C49)+(S1-1), (A2)+(B1)+(C50)+(S1-1),(A2)+(B1)+(C51)+(S1-1),(A2)+(B1)+(C52)+(S1-1),(A2)+(81)+(C53)+(S1-1),(A2)+(B1)+(C54)+(S1-1), (A2)+(B1)+(C55)+(S1-1), (A2)+(B1)+(C56)+(S1-1),(A2)+(B1)+(C57)+(S1-1), (A2)+(B1)+(C58)+(S1-1), (A2)+(B1)+(C59)+(S1-1),(A2)+(B1)+(C60)+(S1-1), (A2)+(B1)+(C61)+(S1-1),(A2)+(B1)+(C62)+(S1-1),(A2)+(B1)+(C63)+(S1-1);

(A2)+(B2)+(C1)+(S1-1), (A2)+(B2)+(C2)+(S1-1), (A2)+(B2)+(C3)+(S1-1),(A2)+(B2)+(C4)+(S1-1), (A2)+(B2)+(C5)+(S1-1), (A2)+(B2)+(C6)+(S1-1),(A2)+(B2)+(C7)+(S1-1), (A2)+(B2)+(C8)+(S1-1), (A2)+(B2)+(C9)+(S1-1),(A2)+(B2)+(C10)+(S1-1), (A2)+(B2)+(C1)+(S1-1),(A2)+(B2)+(C12)+(S1-1),(A2)+(B2)+(C03)+(S1-1),(A2)+(B2)+(ql4)+(S1-1),(A2)+(B2)+(C15)+(S1-1),(A2)+(B2)+(C16)+(S1-1), (A2)+(B2)+(C17)+(S1-1), (A2)+(B2)+(C18)+(S1-1),(A2)+(B2)+(C19)+(S1-1), (A2)+(B2)+(C20)+(S1-1), (A2)+(B2)+(C21)+(S1-1),(A2)+(B2)+(C22)+(S1-1), (A2)+(B2)+(C23)+(S1-1), (A2)+(B2)+(C24)+(S1-1),(A2)+(B2)+(C25)+(S1-1), (A2)+(B2)+(C26)+(S1-1), (A2)+(B2)+(C27)+(S1-1),(A2)+(B2)+(C28)+(S1-1),.(A2)+(B2)+(C29)+(S1-1), (A2)+(B2)+(C30)+(S1-1),(A2)+(B2)+(C31)+(S1-1), (A2)+(B2)+(C32)+(S1-1), (A2)+(B2)+(C33)+(S1-1),(A2)+(B2)+(C34)+(S1-1), (A2)+(B2)+(C35)+(S1-1), (A2)+(B2)+(C36)+(S1-1),(A2)+(B2)+(C37)+(S1-1), (A2)+(B2)+(C38)+(S1-1), (A2)+(B2)+(C39)+(S1-1),(A2)+(B2)+(C40)+(S1-1), (A2)+(B2)+(C41)+(S1-1), (A2)+(B2)+(C42)+(S1-1),(A2)+(B2)+(C43)+(S1-1), (A2)+(B2)+(C44)+(S1-1), (A2)+(B2)+(C45)+(S1-1),(A2)+(B2)+(C46)+(S1-1), (A2)+(B2)+(C47)+(S1-1),(A2)+(B2)+(C48)+(S1-1),(A2)+(B2)+(C49)+(S1-1),(A2)+(B2)+(C50)+(S1-1),(A2)+(B2)+(C51)+(S1-1),(A2)+(B2)+(C52)+(S1-1), (A2)+(B2)+(C53)+(S1-1), (A2)+(B2)+(C54)+(S1-1),(A2)+(B2)+(C55)+(S1-1), (A2)+(B2)+(C56)+(S1-1), (A2)+(B2)+(C57)+(S1-1),(A2)+(B2)+(C58)+(S1-1), (A2)+(B2)+(C59)+(S1-1), (A2)+(B2)+(C60)+(S1-1),(A2)+(B2)+(C61)+(S1-1), (A2)+(B2)+(C62)+(S1-1), (A2)+(B2)+(C63)+(S1-1);

(A1)+(A2)+(B1)+(B2)+(C1)+(S1-1)),(A1)+(A2)+(B1)+(B2)+(C2)+(S1-1),(A1)+(A2)+(B1)+(B2)+(C3)+(S1-1), (A1)+(A2)+(B1)+(B2)+(C4)+(S1-1),(A1)+(A2)+(B1)+(B2)+(C5)+(S1-1), (A1)+(A2)+(B1)+(B2)+(C6)+(S1-1),(A1)+(A2)+(B1)+(B2)+(C7)+(S1-1), (A1)+(A2)+(B1)+(B2)+(C8)+(S1-1),(A1)+(A2)+(B1)+(B2)+(C9)+(S1-1), (A1)+(A2)+(B1)+(B2)+(C10)+(S1-1),(A1)+(A2)+(B1)+(B2),+(C1)+(S1-1), (A1)+(A2)+(B1)+(B2)+(C12)+(S1-1),(A1)+(A2)+(B1)+(B2)+(C13)+(S1-1),(A1)+(A2)+(B1)+(B2)+(C14)+(S1-1)),(A1)+(A2)+(B1)+(B2)+(C15)+(S1-1),(A1)+(A2)+(B1)+(B2)+(C16)+(S1-1),(A1)+(A2)+(B1)+(B2)+(C17)+(S1-1), (A1)+(A2)+(B1)+(B2)+(C18)+(S1-1),(A1)+(A2)+(B1)+(B2)+(C19)+(S1-1), (A1)+(A2)+(B1)+(B2)+(C20)+(S1-1),(A1)+(A2)+(B1)+(B2)+(C21)+(S1-1), (A1)+(A2)+(B1)+(B2)+(C22)+(S1-1),(A1)+(A2)+(B1)+(B2)+(C23)+(S1-1),(A1)+(A2)+(B1)+(B2)+(C24)+(S1-1),(A1)+(A2)+(B1)+(B2)+(C25)+(S1-1),(A1)+(A2)+(B1)+(B2)+(C26)+(S1-1),(A1)+(A2)+(B1)+(B2)+(C27)+(S1-1), (A1)+(A2)+(B1)+(B2)+(C28)+(S1-1),(A1)+(A2)+(B1)+(B2)+(C29)+(S1-1), (A1)+(A2)+(B1)+(B2)+(C30)+(S1-1),(A1)+(A2)+(B1)+(B2)+(C31)+(S1-1), (A1)+(A2)+(B1)+(B2)+(C32)+-(S1-),(A1)+(A2)+(B1)+(B2)+(C33)+(S1-1),(A1)+(A2)+(B1)+(B2)+(C34)+(S1-1),(A1)+(A2)+(B1)+(B2)+(C35)+(S1-1),(A1)+(A2)+(B1)+(B2)+(C36)+(S1-1), (A1)+(A2)+(B1)+(B2)+(C37)+(S1-1),(A1)+(A2)+(B1)+(B2)+(C38)+(S1-1), (A1)+(A2)+(B1)+(B2)+(C39)+(S1-1),(A1)+(A2)+(B1)+(B2)+(C40)+(S1-1),(A1)+(A2)+(B1)+(B2)+(C41)+(S1-1),(A1)+(A2)+(B1)+(B2)+(C42)+(S1-1),(A1)+(A2)+(B1)+(B2)+(C43)+(S1-1),(A1)+(A2)+(B1)+(B2)+(C44)+(S1-1)),(A1)+(A2)+(B1)+(B2)+(C45)+(S1-1),(A1)+(A2)+(B1)+(B2)+(C46)+(S1-1), (A1)+(A2)+(B1)+(B2)+(C47)+(S1-1),(A1)+(A2)+(B1)+(B2)+(C48)+(S1-1), (A1)+(A2)+(B1)+(B2)+(C49)+(S1-1),(A1)+(A2)+(B1)+(B2)+(C50)+(S1-1), (A1)+(A2)+(B1)+(B2)+(C51)+(S1-1),(A1)+(A2)+(B1)+(B2)+(C52)+(S1-1),(A1)+(A2)+(B1)+(B2)+(C53)+(S1-1),(A1)+(A2)+(B1)+(B2)+(C54)+(S1-1)),(A1)+(A2)+(B1)+(B2)+(C55)+(S1-1),(A1)+(A2)+(B1)+(B2)+(C56)+(S1-1), (A1)+(A2)+(B1)+(B2)+(C57)+(S1-1),(A1)+(A2)+(B1)+(B2)+(C58)+(S1-1), (A1)+(A2)+(B1)+(B2)+(C59)+(S1-1),(A1)+(A2)+(B1)+(B2)+(C60)+(S1-1), (A1)+(A2)+(B1)+(B2)+(C61)+(S1-1),(A1)+(A2)+(B1)+(B2)+(C62)+(S1-1),(A1)+(A2)+(B1)+(B2)+(C63)+(S1-1).

(A1)+(B1)+(C1)+(S1-9),(A1)+(B1)+(C2)+(S1-9),(A1)+(B1)+(C3)+(S1-9),(A1)+(B1)+(C4)+(S1-9), (A1)+(B1)+(C5)+(S1-9), (A1)+(B1)+(C6)+(S1-9),(A1)+(B1)+(C7)+(S1-9), (A1)+(B1)+(C8)+(S1-9), (At)+(B1)+(C9)+(S1-9),(A1)+(B1)+(C10)+(S1-9), (A1)+(B1)+(C11)+(S1-9), (A1)+(B1)+(C12)+(S1-9),(A1)+(B1)+(C13)+(S1-9), (A1)+(B1),+(C14)+(S1-9), (A1)+(B1)+(C15)+(S1-9),(A1)+(B1)+(C16)+(S1-9), (A1)+(B1)+(C17)+(S1-9), (A1)+(B1)+(C18)+(S1-9),(A1)+(B1)+(C19)+(S1-9), (A1)+(B1)+(C20)+(S1-9), (A1)+(B1)+(C21)+(S1-9),(A1)+(B1)+(C22)+(S1-9), (A1)+(B1)+(C23)+(S1-9), (A1)+(B1)+(C24)+(S1-9),(A1)+(B1)+(C25)+(S1-9), (A1)+(B1)+(C26)+(S1-9), (A1)+(B1)+(C27)+(S1-9),(A1)+(B1)+(C28)+(S1-9),(A1)+(B1)+(C29)+(S1-9),(A1)+(B1)+(C30)+(S1-9),(A1)+(B1)+(C31)+(S1-9),(A1)+(B1)+(C32)+(S1-9), (A1)+(B1)+(C33)+(S1-9), (A1)+(B1)+(C34)+(S1-9),(A1)+(B1)+(C35)+(S1-9), (A1)+(B1)+(C36)+(S1-9), (A1)+(B1)+(C37)+(S1-9),(A1)+(B1)+(C38)+(S1-9), (A1)+(B1)+(C39)+(S1-9), (A1)+(B1)+(C40)+(S1-9),(A1)+(B1)+(C41)+(S1-9), (A1)+(B1)+(C42)+(S1-9), (A1)+(B1)+(C43)+(S1-9),(A1)+(B1)+(C44)+(S1-9), (A1)+(B1)+(C45)+(S1-9), (A1)+(B1)+(C46)+(S1-9),(A1)+(B1)+(047)+(S1-9), (A1)+(B1)+(C48)+(S1-9), (A1)+(B1)+(C49)+(S1-9),(A1)+(B1)+(C50)+(S1-9), (A1)+(B1)+(C51)+(S1-9), (A1)+(B1)+(C52)+(S1-9),(A1)+(B1)+(C53)+(S1-9), (A1)+(B1)+(C54)+(S1-9), (A1)+(B1)+(C55)+(S1-9),(A1)+(B1)+(C56)+(S1-9), (A1)+(B1)+(C57)+(S1-9), (A1)+(B1)+(C58)+(S1-9),(A1)+(B1)+(C59)+(S1-9), (A1)+(B1)+(C60)+(S1-9), (A1)+(B1)+(C61)+(S1-9),(A1)+(B1)+(C62)+(S1-9), (A1)+(B1)+(C63)+(S1-9);

(A1)+(B2)+(C1)+(S1-9), (A1)+(B2)+(C)+(S1-9), (A1)+(B2)+(C3)+(S1-9),(A1)+(B2)+(C4)+(S1-9), (A1)+(B2)+(C5)+(S1-9), (A1)+(B2)+(C6)+(S1-9),(A1)+(B2)+(C7)+(S1-9), (A1)+(B2)+(C8)+(S1-9), (A1)+(B2)+(C9)+.(S1-9),(A1)+(B2)+(C10)+(S1-9), (A1)+(B2)+(C11)+(S1-9), (A1)+(B2)+(C12)+(S1-9),(A1)+(B2)+(C13)+(S1-9), (A1)+(B2)+(C14)+(S1-9), (A1)+(B2)+(C15)+(S1-9),(A1)+(B2)+(C16)+(S1-9), (A1)+(B2)+(C17)+(S1-9), (A1)+(B2)+(C18)+(S1-9),(A1)+(B2)+(C19)+(S1-9), (A1)+(B2)+(C20)+(S1-9), (A1)+(B2)+(C21)+(S1-9),(A1)+(B2)+(C22)+(S1-9), (A1)+(B2)+(C23)+(S1-9), (A1)+(B2)+(C24)+(S1-9),(A1)+(B2)+(C25)+(S1-9), (A1)+(B2)+(C26)+(S1-9), (A1)+(B2)+(C27)+(S1-9),(A1)+(B2)+(C28)+(S1-9), (A1)+(B2)+(C29)+(S1-9), (A1)+(B2)+(C30)+(S1-9),(A1)+(B2)+(C31)+(S1-9), (A1)+(B2)+(C32)+(S1-9), (A1)+(B2)+(C33)+(S1-9),(A1)+(B2)+(C34)+(S1-9), (A1)+(B2)+(C35)+(S1-9), (A1)+(B2)+(C36)+(S1-9),(A1)+(B2)+(C37)+(S1-9), (A1)+(B2)+(C38)+(S1-9), (A1)+(B2)+(C39)+(S1-9),(A1)+(B2)+(C40)+(S1-9), (A1)+(B2)+(C41)+(S1-9), (A1)+(B2)+(C42)+(S1-9),(A1)+(B2)+(C43)+(S1-9), (A1)+(B2)+(C44)+(S1-9), (A1)+(B2)+(C45)+(S1-9),(A1)+(B2)+(C46)+(S1-9), (A1)+(B2)+(C47)+(S1-9), (A1)+(B2)+(C48)+(S1-9),(A1)+(B2)+(C49)+(S1-9), (A1)+(B2)+(C50)+(S1-9), (A1)+(B2)+(C51)+(S1-9),(A1)+(B2)+(C52)+(S1-9), (A1)+(B2)+(C53)+(S1-9), (A1)+(B2)+(C54)+(S1-9),(A1)+(B2)+(C55)+(S1-9), (A1)+(B2)+(C56)+(S1-9), (A1)+(B2)+(C57)+(S1-9),(A1)+(B2)+(C58)+(S1-9), (A1)+(B2)+(C59)+(S1-9), (A1)+(B2)+(C60)+(S1-9),(A1)+(B2)+(C61)+(S1-9), (A1)+(B2)+(C62)+(S1-9), (A1)+(B2)+(C63)+(S1-9);

(A2)+(B1)+(C1)+(S1-9), (A2)+(B1)+(C2)+(S1-9), (A2)+(B1)+(C3)+(S1-9),(A2)+(B1)+(C4)+(S1-9), (A2)+(B1)+(C5)+(S1-9), (A2)+(B1)+(C6)+(S1-9),(A2)+(B1)+(C7)+(S1-9),(A2)+(B1)+(C8)+(S1-9),(A2)+(B1)+(C9)+(S1-9),(A2)+(B1)+(C10)+(S1-9),(A2)+(B1)+(C11)+(S1-9),(A2)+(B1)+(C12)+(S1-9),(A2)+(B1)+(C13)+(S1-9),(A2)+(B1)+(C14)+(S1-9),(A2)+(B1)+(C15)+(S1-9),(A2)+(B1)+(C16)+(S1-9), (A2)+(B1)+(C17)+(S1-9), (A2)+(B1)+(C18)+(S1-9),(A2)+(B1)+(C19)+(S1-9), (A2)+(B1)+(C20)+(S1-9), (A2)+(B1)+(C21)+(S1-9),(A2)+(B1)+(C22)+(S1-9), (A2)+(B1)+(C23)+(S1-9), (A2)+(B1)+(C24)+(S1-9),(A2)+(B1)+(C25)+(S1-9), (A2)+(B1)+(C26)+(S1-9), (A2)+(B1)+(C27)+(S1-9),(A2)+(B1)+(C28)+(S1-9), (A2)+(B1)+(C29)+(S1-9), (A2)+(B1)+(C30)+(S1-9),(A2)+(B1)+(C31)+(S1-9), (A2)+(B1)+(C32)+(S1-9), (A2)+(B1)+(C33)+(S1-9),(A2)+(B1)+(C34)+(S1-9), (A2)+(B1)+(C35)+(S1-9), (A2)+(B1)+(C36)+(S1-9),(A2)+(B1)+(C37)+(S1-9), (A2)+(B1)+(C38)+(S1-9), (A2)+(B1)+(C39)+(S1-9),(A2)+(B1)+(C40)+,(S1-9),(A2)+(B1)+(C41)+(S1-9),(A2)+(B1)+(C42)+(S1-9),(A2)+(B1)+(C43)+(S1-9), (A2)+(B1)+(C44)+(S1-9), (A2)+(B1)+(C45)+(S1-9),(A2)+(B1)+(C46)+(S1-9), (A2)+(B1)+(C47)+(S1-9), (A2)+(B1)+(C48)+(S1-9),(A2)+(B1)+(C49)+(S1-9), (A2)+(B1)+(C50)+(S1-9), (A2)+(B1)+(C51)+(S1-9),(A2)+(B1)+(C52)+(S1-9), (A2)+(B1)+(C53)+(S1-9), (A2)+(B1)+(C54)+(S1-9),(A2)+(B1)+(C55)+(S1-9), (A2)+(B1)+(C56)+(S1-9), (A2)+(B1)+(C57)+(S1-9),(A2)+(B1)+(C58)+(S1-9),(A2)+(B1)+(C59)+(S1-9),(A2)+(B1)+(C60)+(S1-9),(A2)+(B1)+(C61)+(S1-9),(A2)+(B1)+(C62)+(S1-9),(A2)+(B1)+(C63)+(S 1-9);

(A2)+(B2)+(C1)+(S1-9), (A2)+(B2)+(C2)+(S1-9), (A2)+(B2)+(C3)+(S1-9),(A2)+(B2)+(C4)+(S1-9), (A2)+(B2)+(C5)+(S1-9), (A2)+(B2)+(C6)+(S1-9),(A2)+(B2)+(C7)+(S1-9), (A2)+(B2)+(C8)+(S1-9), (A2)+(B2)+(C9)+(S1-9),(A2)+(B2)+(C10)+(S1-9), (A2)+(B2)+(C11)+(S1-9), (A2)+(B2)+(C12)+(S1-9),(A2)+(B2)+(C13)+(S1-9), (A2)+(B2)+(C14)+(S1-9), (A2)+(B2)+(C15)+(S1-9),(A2)+(B2)+(C6)+(S1-9), (A2)+(B2)+(C7)+(S1-9), (A2)+(B2)+(C18)+(S1-9),(A2)+(B2)+(C19)+(S1-9), (A2)+(B2)+(C20)+(S1-9), (A2)+(B2)+(C21)+(S1-9),(A2)+(B2)+(C22)+(S1-9), (A2)+(B2)+(C23)+(S1-9), (A2)+(B2)+(C24)+(S1-9),(A2)+(B2)+(C25)+(S1-9), (A2)+(B2)+(C26)+(S1-9), (A2)+(B2)+(C27)+(S1-9),(A2)+(B2)+(C28)+(S1-9), (A2)+(B2)+(C29)+(S1-9), (A2)+(B2)+(C30)+(S1-9),(A2)+(B2)+(C31)+(S1-9), (A2)+(B2)+(C32)+(S1-9), (A2)+(B2)+(C33)+(S1-9),(A2)+(B2)+(C34)+(S1-9), (A2)+(B2)+(C35)+(S1-9), (A2)+(B2)+(C36)+(S1-9),(A2)+(B2)+(C37)+(S1-9), (A2)+(B2)+(C38)+(S1-9), (A2)+(B2)+(C39)+(S1-9),(A2)+(B2)+(C40)+(S1-9), (A2)+(B2)+(C41)+(S1-9), (A2)+(B2)+(C42)+(S1-9),(A2)+(B2)+(C43)+(S1-9), (A2)+(B2)+(C44)+(S1-9),(A2)+(B2)+(C45)+(S1-9),,(A2)-+(B2)+(C46)+(S1-9), (A2)+(B2)+(C47)+(S1-9),(A2)+(B2)+(C48)+(S1-9), (A2)+(B2)+(C49)+(S1-9), (A2)+(B2)+(C50)+(S1-9),(A2)+(B2)+(C51)+(S1-9), (A2)+(B2)+(C52)+(S1-9), (A2)+(B2)+(C53)+(S1-9),(A2)+(B2)+(C54)+(S1-9), (A2)+(B2)+(C55)+(S1-9), (A2)+(B2)+(C56)+(S1-9),(A2)+(B2)+(C57)+(S1-9), (A2)+(B2)+(C58)+(S1-9), (A2)+(B2)+(C59)+(S1-9),(A2)+(B2)+(C60)+(S1-9), (A2)+(B2)+(C61)+(S1-9), (A2)+(B2)+(C62)+(S1-9),(A2)+(B2)+(C63)+(S1-9);(A1)+(A2)+(B1)+(B2)+(C1)+(S1-9),(A1)+(A2)+(B)+(B2)+(C2)+(S1-9),(A1)+(A2)+(B1)+(B2)+(C3)+(S1-9), (A1)+(A2)+(B1)+(B2)+(C4)+(S1-9),(A1)+(A2)+(B1)+(B2)+(C5)+(S1-9), (A1)+(A2)+(B1)+(B2)+(C6)+(S1-9),(A1)+(A2)+(B1)+(B2)+(C7)+(S1-9), (A1)+(A2)+(B1)+(B2)+(C8)+(S1-9),(A1)+(A2)+(B1)+(B2)+(C9)+(S1-9),(A1)+(A2)+(B1)+(B2)+(C10)+(S1-9),(A1)+(A2)+(B1)+(B2)+(C11)+(S1-9),(A1)+(A2)+(B1)+(B2)+(C12)+(S1-9),(A1)+(A2)+(B1)+(B2)+(C13)+(S1-9),(A1)+(A2)+(B1)+(B2)+(C14)+(S1-9),(A1)+(A2)+(B1)+(B2)+(C5)+(S1-9), (A1)+(A2)+(B1)+(B2)+(C16)+(S1-9),(A1)+(A2)+(B1)+(B2)+(C17)+(S1-9),(A1)+(A2)+(B1)+(B2)+(C18)+(S19),(A1)+(A2)+(B1)+(B2)+(C19)+(S1-9),(A1)+(A2)+(B1)+(B2)+(C20)+(S1-9),(A1)+(A2)+(B1)+(B2)+(C21)+(S1-9), (A1)+(A2)+(B1)+(B2)+(C22)+(S1-9),(A1)+(A2)+(B)+(B2)+(C23)+(S1-9), (A1)+(A2)+(B1)+(B2)+(C24)+(S1-9),(A1)+(A2)+(B1)+(B2)+(C25)+(S1-9), (A1)+(A2)+(B1)+(B2)+(C26)+(S1-9),(A1)+(A2)+(B1)+(B2)+(C27)+(S1-9),(A1)+(A2)+(B1)+(B2)+(C28)+(S1-9),(A1)+(A2)+(B1)+(B2)+(C29)+(S1-9),(A1)+(A2)+(B1)+(B2)+(C30)+(S1-9),(A1)+(A2)+(B1)+(B2)+(C31)+(S1-9), (A1)+(A2)+(B1)+(B2)+(C32)+(S1-9),(A1)+(A2)+(B1)+(B2)+(C33)+(S1-9), (A1)+(A2)+(B1)+(B2)+(C34)+(S1-9),(A1)+(A2)+(B1)+(B2)+(C35)+(S1-9), (A1)+(A2)+(B1)+(B2)+(C36)+(S1-9),(A1)+(A2)+(B1)+(B2)+(C37)+(S1-9), (A1)+(A2)+(B1)+(B2)+(C38)+(S1-9),(A1)+(A2)+(B1)+(B2)+(C39)+(S1-9), (A1)+(A2)+(B1)+(B2)+(C40)+(S1-9),(A1)+(A2)+(B1)+(B2)+(C41)+(S1-9), (A1)+(A2)+(B1)+(B2)+(C42)+(S1-9),(A1)+(A2)+(B1)+(B2)+(C43)+(S1-9), (A1)+(A2)+(B1)+(B2)+(C44)+(S1-9),(A1)+(A2)+(B1)+(B2)+(C45)+(S1-9), (A1)+(A2)+(B1)+(B2)+(C46)+(S1-9),(A1)+(A2)+(B1)+(B2)+(C47)+(S1-9),(A1)+(A2)+(B1)+(B2)+(C48)+(S1-9),(A1)+(A2)+(B1)+(B2)+(C49)+(S1-9),(A1)+(A2)+(B1)+(B2)+(C50)+(S1-9),-(A1)+(A2)+(B1)+(B2)+(C51)+(S1-9),(A1)+(A2)+(B1)+(B2)+(C52)+(S1-9), (A1)+(A2)+(B1)+(B2)+(C53)+(S1-9),(A1)+(A2)+(B1)+(B2)+(C54)+(S1-9), (A1)+(A2)+(B1)+(B2)+(C55)+(S1-9),(A1)+(A2)+(B1)+(B2)+(C56)+(S1-9),(A1)+(A2)+(B1)+(B2)+(C57)+(S1-9),(A1)+(A2)+(B1)+(B2)+(C58)+(S1-9),(A1)+(A2)+(B1)+(B2)+(C59)+(S1-9), (A1)+(A2)+(B1)+(B2)+(C60)+(S1-9),(A1)+(A2)+(B1)+(B2)+(C61)+(S1-9), (A1)+(A2)+(B)+(B2)+(C62)+(S1-9),(A1)+(A2)+(B1).+(B2)+(C63)+(S1-9).

(A1)+(B1)+(C1)+(S2-1),(A1)+(B1)+(C2)+(S2-1), (A1)+(B1)+(C3)+(S2-1),(A1)+(B1)+(C4)+(S2-1), (A1)+(B1)+(C5)+(S2-1), (A1)+(B1)+(C6)+(S2-1),(A1)+(B1)+(C7)+(S2-1), (A1)+(B1)+(C8)+(S2-1), (A1)+(B1)+(C9)+(S2-1),(A1)+(B1)+(C10)+(S2-1), (A1)+(B1)+(C1)+(S2-1), (A1)+(B1)+(C12)+(S2-1),(A1)+(B1)+(C13)+(S2-1), (A1)+(B1)+(C14)+(S2-1), (A1)+(B1)+(C15)+(S2-1),(A1)+(B1)+(C16)+(S2-1), (A1)+(B1)+(C17)+(S2-1),(A1)+(B1)+(C18)+(S2-1),(A1)+(B1)+(C19)+(S2-1),(A1)+(B1)+(C20)+(S2-1),(A1)+(B1)+(C21)+(S2-1), (A1)+.(B1)+(C22)+(S2-1), (A1)+(B1)+(C23)+(S2-1),(A1)+(B1)+(C24)+(S2-1), (A1)+(B1)+(C25)+(S2-1), (A1)+(B1)+(C26)+(S2-1),(A1)+(B1)+(C27)+(S2-1), (A1),+(B1)+(C28)+(S2-1), (A1)+(B1)+(C29)+(S2-1),(A1)+(B1)+(C30)+(S2-1), (A1)+(B1)+(C31)+(S2-1), (A1)+(B1)+(C32)+(S2-1),(A1)+(B1)+(C33)+(S2-1), (A1)+(B1)+(C34)+(S2-1), (A1)+(B1)+(C35)+(S2-1),(A1)+(B1)+(C36)+(S2-1), (A1)+(B1)+(C37)+(S2-1), (A1)+(B1)+(C38)+(S2-1),(A1)+(B1)+(C39)+(S2-1), (A1)+(B1)+(C40)+(S2-1), (A1)+(B1)+(C41)+(S2-1),(A1)+(B1)+(C42)+(S2-1), (A1)+(B1)+(C43)+(S2-1), (A1)+(B1)+(C44)+(S2-1),(A1)+(B1)+(C45)+(S2-1), (A1)+(B1)+(C46)+(S2-1), (A1)+(B1)+(C47)+(S2-1),(A1)+(B1)+(C48)+(S2-1), (A1)+(B1)+(C49)+(S2-1), (A1)+(B1)+(C50)+(S2-1),(A1)+(B1)+(C51)+(S2-1), (A1)+(B1)+(C52)+(S2-1), (A1).+(B1)+(C53)+(S2-1),(A1)+(B1)+(C54)+(S2-1), (A1)+(B1)+(C55)+(S2-1), (A1)+(B1)+(C56)+(S2-1),(A1)+(B1)+(C57)+(S2-1), (A1)+(B1)+(C58)+(S2-1), (A1)+(B1)+(C59)+(S2-1),(A1)+(B1)+(060)+(S2-1), (A1)+(B1)+(C61)+(S2-1), (A1)+(B1)+(C62)+(S2-1),(A1)+(B1)+(C63)+(S2-1);

(A1)+(B2)+(C1)+(S2-1), (A1)+(B2)+(C)+(S2-1), (A1)+(B2)+(C3)+(S2-1),(A1)+(B2)+(C4)+(S2-1), (A1)+(B2)+(C5)+(S2-1), (A1)+(B2)+(C6)+(S2-1),(A1)+(B2)+(C7)+(S2-1), (A1)+(B2)+(C8)+(S2-1), (A1)+(B2)+(C9)+(S2-1),(A1)+(B2)+(C10)+(S2-1), (A1)+(B2)+(C11)+(S2-1), (A1)+(B2)+(C12)+(S2-1),(A1)+(B2)+(C13)+(S2-1), (A1)+(B2)+(C14)+(S2-1), (A1)+(B2)+(C15)+(S2-1),(A1)+(B2)+(C16)+(S2-1), (A1)+(B2)+(C17)+(S2-1), (A1)+(B2)+(C18)+(S2-1),(A1)+(B2)+(C19)+(S2-1), (A1)+(B2)+(C20)+(S2-1), (A1)+(B2)+(C21)+(S2-1),(A1)+(B2)+(C22)+(S2-1), (A1)+(B2)+(C23)+(S2-1), (A1)+(B2)+(C24)+(S2-1),(A1)+(B2)+(C25)+(S2-1), (A1)+(B2)+(C26)+(S2-1), (A1)+(B2)+(C27)+(S2-1),(A1)+(B2)+(C28)+(S2-1), (A1)+(B2)+(C29)+(S2-1), (A1)+(B2)+(C30)+(S2-1),(A1)+(B2)+(C31)+(S2-1), (A1)+(B2)+(C32)+(S2-1), (A1)+(B2)+(C33)+(S2-1),(A1)+(B2)+(C34)+(S2-1), (A1)+(B2)+(C35)+(S2-1), (A1)+(B2)+(C36)+(S2-1),(A1)+(B2)+(C37)+(S2-1), (A1)+(B2)+(C38)+(S2-1), (A1)+(B2)+(C39)+(S2-1),(A1)+(B2)+(C40)+(S2-1), (A1)+(B2)+(C41)+(S2-1), (A1)+(B2)+(C42)+(S2-1),(A1)+(B2)+(C43)+(S2-1), (A1)+(B2)+(C44)+(S2-1), (A1)+(B2)+(C45)+(S2-1),(A1)+(B2)+(C46)+(S2-1), (A1)+(B2)+(C47)+(S2-1), (A1)+(B2)+(C48)+(S2-1),(A1)+(B2)+(C49)+(S2-1), (A1)+(B2)+(C50)+(S2-1), (A1)+(B2)+(C51)+(S2-1),(A1)+(B2)+(C52)+(S2-1), (A1)+(B2)+(C53)+(S2-1), (A1)+(B2)+(C54)+(S2-1),(A1)+(B2)+(C55)+(S2-1), (A1)+(B2)+(C56)+(S2-1), (A1)+(B2)+(C57)+(S2-1),(A1)+(B2)+(C58)+(S2-1), (A1)+(B2)+(C59)+(S2-1), (A1)+(B2)+(C60)+(S2-1),(A1)+(B2)+(C61)+(S2-1), (A1)+(B2)+(C62)+(S2-1), (A1)+(B2)+(C63)+(S2-1);

(A2)+(B1)+(C1)+(S2-1), (A2)+(B1)+(C2)+(S2-1), (A2)+(B1)+(C3)+(S2-1),(A2)+(B1)+(C4)+(S2-1), (A2)+(B1)+(C5)+(S2-1), (A2)+(B1)+(C6)+(S2-1),(A2)+(B1)+(C7)+(S2-1), (A2)+(B1)+(C8)+(S2-1), (A2)+(B1)+(C9)+(S2-1),(A2)+(B1)+(C10)+(S2-1), (A2)+(B1)+(C11)+(S2-1), (A2)+(B1)+(C12)+(S2-1),(A2)+(B1)+(C13)+(S2-1), (A2)+(B1)+(C14)+(S2-1), (A2)+(B1)+(C15)+(S2-1),(A2)+(B1)+(C16)+(S2-1), (A2)+(B1)+(C17)+(S2-1), (A2)+(B1)+(C18)+(S2-1),(A2)+(B1)+(C19)+(S2-1), (A2)+(B1)+(C20)+(S2-1), (A2)+(B1)+(C21)+(S2-1),(A2)+(B1)+(C22)+(S2-1), (A2)+(B1)+(C23)+(S2-1), (A2)+(B1)+(C24)+(S2-1),(A2-)+(B1)+(C25)+(S2-1), (A2)+(B)+(C26)+(S2-1), (A2)+(B1)+(C27)+(S2-1),(A2)+(B1)+(C28)+(S2-1), (A2)+(B1)+(C29)+(S2-1), (A2)+(B1)+(C30)+(S2-1),(A2)+(B1)+(C31)+(S2-1), (A2)+(B1)+(C32)+(S2-1), (A2)+(B1)+(C33)+(S2-1),(A2)+(B1)+(C34)+(S2-1), (A2)+(B1)+(C35)+(S2-1), (A2)+(B1)+(C36)+(S2-1),(A2)+(B1)+(C37)+,(S2-1), (A2)+(B1)+(C38)+(S2-1), (A2)+(B1)+(C39)+(S2-1),(A2)+(B1)+(C40)+(S2-1), (A2)+(B1)+(C41)+(S2-1), (A2)+(B1)+(C42)+(S2-1),(A2)+(B1)+(C43)+(S2-1), (A2)+(B1)+(C44)+(S2-1), (A2)+(B1)+(C45)+(S2-1),(A2)+(B1)+(C46)+(S2-1), (A2)+(B1)+(C47)+(S2-1), (A2)+(B1)+(C48)+(S2-1),(A2)+(B1)+(C49)+(S2-1), (A2)+(B1)+(C50)+(S2-1), (A2)+(B1)+(C51)+(S2-1),(A2)+(B1)+(C52)+(S2-1), (A2)+(B1)+(C53)+(S2-1), (A2)+(B1)+(C54)+(S2-1),(A2)+(B1)+(C55)+(S2-1), (A2)+(B1)+(C56)+(S2-1), (A2)+(B1)+(C57)+(S2-1),(A2)+(B1)+(C58)+(S2-1), (A2)+(B1)+(C59)+(S2-1), (A2)+(B1)+(C60)+(S2-1),(A2)+(B1)+(C61)+(S2-1), (A2)+(B1)+(C62)+(S2-1), (A2)+(B1)+(C63)+(S2-1);

(A2)+(B2)+(C1)+(S2-1), (A2)+(B2)+(C2)+(S2-1), (A2)+(B2)+(C3)+(S2-1),(A2)+(B2)+(C4)+(S2-1), (A2)+(B2)+(C5)+(S2-1), (A2)+(B2)+(C6)+(S2-1),(A2)+(B2)+(C7)+(S2-1), (A2)+(B2)+(C8)+(S2-1), (A2)+(B2)+(C9)+(S2-1),(A2)+(B2)+(C10)+(S2-1), (A2)+(B2)+(C11)+(S2-1), (A2)+(B2)+(C12)+(S2-1),(A2)+(B2)+(C13)+(S2-1), (A2)+(B2)+(C14)+(S2-1), (A2)+(B2)+(C15)+(S2-1),(A2)+(B2)+(C16)+(S2-1), (A2)+(B2)+(C17)+(S2-1), (A2)+(B2)+(C18)+(S2-1),(A2)+(B2)+(C19)+(S2-1), (A2)+(B2)+(C20)+(S2-1) (A2)+(B2)+(C21)+(S2-1),(A2)+(B2)+(C22)+(S2-1), (A2)+(B2)+(C23)+(S2-1), (A2)+(B2)+(C24)+(S2-1),(A2)+(B2)+(C25)+(S2-1), (A2)+(B2)+(C26)+(S2-1), (A2)+(B2)+(C27)+(S2-1),(A2)+(B2)+(C28)+(S2-1), (A2)+(B2)+(C29)+(S2-1), (A2)+(B2)+(C30)+(S2-1),(A2)+(B2)+(C31)+(S2-1), (A2)+(B2)+(C32)+(S2-1), (A2)+(B2)+(C33)+(S2-1),(A2)+(B2)+(C34)+(S2-1), (A2)+(B2)+(C35)+(S2-1), (A2)+(B2)+(C36)+(S2-1),(A2)+(B2)+(C37)+(S2-1), (A2)+(B2)+(C38)+(S2-1), (A2)+(B2)+(C39)+(S2-1),(A2)+(B2)+(C40)+(S2-1), (A2)+(B2)+(C41)+(S2-1), (A2)+(B2)+(C42)+(S2-1),(A2)+(B2)+(C43)+(S2-1), (A2)+(B2)+(C44)+(S2-1), (A2)+(B2)+(C45)+(S2-1),(A2)+(B2)+(C46)+(S2-1), (A2)+(B2)+(C47)+(S2-1), (A2)+(B2)+(C48)+(S2-1),(A2)+(B2)+(C49)+(S2-1), (A2)+(B2)+(C50)+(S2-1), (A2)+(B2)+(C51)+(S2-1),(A2)+(B2)+(C52)+.(S2-1), (A2)+(B2)+(C53)+(S2-1), (A2)+(B2)+(C54)+(S2-1),(A2)+(B2)+(C55)+(S2-1), (A2)+(B2)+(C56)+(S2-1), (A2)+(B2)+(C57)+(S2-1),(A2)+(B2)+(C58)+(S2-1), (A2)+(B2)+(C59)+(S2-1), (A2)+(B2)+(C60)+(S2-1),(A2)+(B2)+(C61)+(S2-1), (A2)+(B2)+(C62)+(S2-1), (A2)+(B2)+(C63)+(S2-1);

(A1)+(A2)+(B1)+(B2)+(C1)+(S2-1), (A1)+(A2)+(B1)+(B2)+(C2)+(S2-1),(A1)+(A2)+(B1)+(B2)+(C3)+(S2-1),(A1)+(A2)+(B1)+(B2)+(C4)+(S2-1),(A1)+(A2)+(B1)+(B2)+(C5)+(S2-1), (A1)+(A2)+(B1)+(B2)+(C6)+(S2-1),(A1)+(A2)+(B1)+(B2)+(C7)+(S2-1), (A1)+(A2)+(B1)+(B2)+(C8)+(S2-1),(A1)+(A2)+(B1)+(B2)+(C9)+(S2-1), (A1)+(A2)+(B1)+(B2)+(C10)+(S2-1),(A1)+(A2)+(B1)+(B2)+(C11)+(S2-1),(A1)+(A2)+(B1),+(B2)+(C12)+(S2-1),(A1)+(A2)+(B1)+(B2)+(C13)+(S2-1),(A1)+(A2)+(B1)+(B2)+(C14)+(S2-1),(A1)+(A2)+(B1)+(B2)+(C15)+(S2-1), (A1)+(A2)+(B1)+(B2)+(C16)+(S2-1),(A1)+(A2)+(B1)+(B2)+(C17)+(S2-1), (A1)+(A2)+(B1)+(B2)+(C18)+(S2-1),(A1)+(A2)+(B1)+(B2)+(C19)+(S2-1), (A1)+(A2)+(B1)+(B2)+(C20)+(S2-1),(A1)+(A2)+(B1)+(B2)+(C21)+(S2-1), (A1)+(A2)+(B1)+(B2)+(C22)+(S2-1),(A1)+(A2)+(B1)+(B2)+(C23)+(S2-1), (A1)+(A2)+(B1)+(B2)+(C24)+(S2-1),(A1)+(A2)+(B1)+(B2)+(C25)+(S2-1), (A1)+(A2)+(B1)+(B2)+(C26)+(S2-1),(A1)+(A2)+(B1)+(B2)+(C27)+(S2-1), (A1)+(A2)+(B1)+(B2)+(C28)+(S2-1),(A1)+(A2)+(B1)+(B2)+(C29)+(S2-1),(A1)+(A2)+(B1)+(B2)+(C30)+(S2-1),(A1)+(A2)+(B1)+(B2)+(C31)+(S2-1),(A1)+(A2)+(B1)+(B2)+(C32)+(S2-1),(A1)+(A2)+(B1)+(B2)+(C33)+(S2-1), (A1)+(A2)+(B1)+(B2)+(C34)+(S2-1),(A1)+(A2)+(B1)+(B2)+(C35)+(S2-1), (A1)+(A2)+(B1)+(B2)+(C36)+(S2-1),(A1)+(A2)+(B1)+(B2)+(C37)+(S2-1), (A1)+(A2)+(B1)+(B2)+(C38)+(S2-1),(A1)+(A2)+(B1)+(B2)+(C39)+(S2-1), (A1)+(A2)+(B1)+(B2)+(C40)+(S2-1),(A1)+(A2)+(B1)+(B2)+(C41)+(S2-1), (A1)+(A2)+(B1)+(B2)+(C42)+(S2-1),(A1)+(A2)+(B1)+(B2)+(C43)+(S2-1), (A1)+(A2)+(B1)+(B2)+(C44)+(S2-1),(A1)+(A2)+(B1)+(B2)+(C45)+(S2-1), (A1)+(A2)+(B1)+(B2)+(C46)+(S2-1),(A1)+(A2)+(B1)+(B2)+(C47)+(S2-1), (A1)+(A2)+(B1)+(B2)+(C48)+(S2-1),(A1)+(A2)+(B1)+(B2)+(C49)+(S2-1), (A1)+(A2)+(B1)+(B2)+(C50)+(S2-1),(A1)+(A2)+(B1)+(B2)+(C51)+(S2-1), (A1)+(A2)+(B1)+(B2)+(C52)+(S2-1),(A1)+(A2)+(B1)+(B2)+(C53)+(S2-1), (A1)+(A2)+(B1)+(B2)+(C54)+(S2-1),(A1)+(A2)+(B1)+(B2)+(C55)+(S2-1), (A1)+(A2)+(B1)+(B2)+(C56)+(S2-1),(A1)+(A2)+(B1)+(B2)+(C57)+(S2-1), (A1)+(A2)+(B1)+(B2)+(C58)+(S2-1),(A1)+(A2)+(B1)+(B2)+(C59)+(S2-1), (A1)+(A2)+(B1)+(B2)+(C60)+(S2-1),(A1)+(A2)+(B1)+(B2)+(C61)+(S2-1), (A1)+(A2)+(B1)+(B2)+(C62)+(S2-1),(A1)+(A2)+(B1)+(B2)+(C63)+(S2-1).

It may make sense to combine one or more herbicides (A) with one or moreherbicides (B) and one or more herbicides (C), for example one herbicide(A) with one herbicide (B) and one or more herbicide (C). Herbicidecombinations according to the invention, which contain more than oneherbicide (C), are, for example, those which contain the followingherbicide combinations as component (C): C3 +C7, C2 +C7, C3 +C10, C5+C7, C3 +C10 +C33, C20 +C37, C7 +C15 +C16 +C39, C15 +C16 +C25 +C39, C16+C41, C10 +C36, C10 +C33, C10 +C34, C33 +C34, C33+C42, C23 +C24, C3 +C7+C36, C3 +C7 +C18 or C3 +C10 +C15, where the preferred component (A) and(B) which is present is the compounds (A1)+(B1), (A1)+(B2), (A2)+(B1) or(A2)+(B2), in particular (A1)+(B2), and where a safener such as (S1-1),(S1-9) or (S2-1), in particular (S1-9) may additionally be present.Furthermore, the combinations according to the invention may be employedtogether with other agrochemical active compounds, for example from thegroup of the safeners, fungicides, insecticides and plant growthregulators, or additives and formulation auxiliaries conventionally usedin crop protection. Additives are, for example, fertilizers andcolorants. The ranges of application rates and the application ratiosmentioned above are preferred in each case in this context.

The combinations according to the invention (=herbicidal compositions)have an outstanding herbicidal activity against a broad spectrum ofeconomically important monocotyledonous and dicotyledonous harmfulplants. The active ingredients also act efficiently on perennial weedswhich produce shoots from rhizomes, rootstocks or other perennial organsand which are difficult to control. In this context, it does not matterwhether the substances are applied before sowing, pre-emergence orpost-emergence. Post-emergence application, or early post-sowingpre-emergence application, is preferred.

Specifically, examples may be mentioned of some representatives of themonocotyledonous and dicotyledonous weed flora which can be controlledby the compounds according to the invention, without the enumerationbeing a restriction to certain species.

Examples of weed species on which the herbicidal compositions actefficiently are, from amongst the monocotyledonous weed species, Avenaspp., A1opecurus spp:, Apera spica venti, Brachiaria spp., Digitariaspp., Lolium spp., Equinochloa spp., Panicum spp., Phalaris spp., Poaspp., Setaria spp. and Cyperus species from the annual group, and,amongst the perennial species, Agropyron, Cynodon, Imperata and Sorghumand also perennial Cyperus species.

In the case of the dicotyledonous weed species, the spectrum of actionextends to species such as, for example, Abutilon spp., Amaranthus spp.,Chenopodium spp., Chrysanthemum spp., Galium spp., Ipomoea spp., Kochiaspp., Lamium spp., Matricaria spp., Pharbitis spp., Polygonum spp., Sidaspp., Sinapis spp., Solanum spp., Stellaria spp., Veronica spp. andViola spp., Xanthium spp., amongst the annuals, and Convolvulus,Cirsium, Rumex and Artemisia in the case of the perennial weeds.

If the compounds according to the invention are applied to the soilsurface before germination, then the weed seedlings are either preventedcompletely from emerging, or the weeds grow until they have reached thecotyledon stage but then their growth stops, and, eventually, afterthree to four weeks have elapsed, they die completely.

If the active ingredients are applied post-emergence to the green partsof the plants, growth likewise stops drastically a very short time afterthe treatment and the weed plants remain at the growth stage of thepoint of time of application, or they die completely after a certaintime, so that in this manner competition by the weeds, which is harmfulto the crop plants, is eliminated at a very early point in time and in asustained manner.

The herbicidal compositions according to the invention are distinguishedby a rapidly commencing and long-lasting herbicidal action. As a rule,the rainfastness of the active ingredients in the combinations accordingto the invention is advantageous. A particular advantage is that thedosages of the compounds (A), (B) and (C) which are used in thecombinations and are effective, can be adjusted to such a low quantitythat their soil action is optimally low. This does not only allow themto be employed in sensitive crops in the first place, but groundwatercontaminations are virtually avoided. The active-ingredient combinationaccording to the invention allows the application rate of the activeingredients required to be reduced considerably.

When herbicides of the type (A)+(B)+(C) are used jointly, superadditive(=synergistic) effects are observed in a preferred embodiment. Thismeans that the effect in the combinations exceeds the expected total ofthe effects of the individual herbicides employed. The synergisticeffects allow the application rate to be reduced, a broader spectrum ofbroad-leaved weeds and grass weeds to be controlled, the herbicidalaction to take place more rapidly, the duration of action to be longer,the harmful plants to be controlled better while using only one, or few,applications, and the application period which is possible to beextended. In some cases, use of the compositions also reduces the amountof harmful constituents, such as nitrogen or oleic acid, and their entryinto the ground.

The abovementioned properties and advantages are necessary for weedcontrol practice to keep agricultural crops free from undesiredcompeting plants and thus to guarantee and/or increase the yields fromthe qualitative and quantitative point of view. These novel combinationsmarkedly exceed the technical state of the art with a view to theproperties described.

While the combinations according to the invention have an outstandingherbicidal activity against monocotyledonous and dicotyledonous weeds,the crop plants are damaged only to a minor extent, if at all.

Moreover, some of the compositions according to the invention haveoutstanding growth-regulatory properties on the crop plants. They engagein the plants metabolism in a regulatory manner and can thus be employedfor provoking directed effects on plant constituents and to facilitateharvesting such as for example by triggering desiccation and stuntedgrowth. Moreover, they are also suitable for the general control andinhibition of undesired vegetative growth without simultaneouslydestroying the plants. An inhibition of vegetative growth is veryimportant in a large number of monocotyledonous and dicotyledonous cropssince lodging can thus be reduced, or prevented completely.

Owing to their herbicidal and plant-growth-regulatory properties, thecompositions according to the invention can be employed for controllingharmful plants in genetically modified crop plants or crop plantsobtained by mutation/selection. These crop plants are distinguished as amole by particular, advantageous properties, such as resistances toherbicidal compositions or resistances to plant diseases or causativeagents of plant diseases such as particular insects or microorganismssuch as fungi, bacteria or viruses. Other particular properties relate,for example, to the harvested material with regard to quantity, quality,storability, composition and specific constituents. Thus, for example,transgenic plants are known whose starch content is increased or whosestarch quality is altered, or those where the harvested material has adifferent fatty acid composition.

Conventional methods of generating novel plants which have modifiedproperties in comparison to plants occurring to date consist, forexample, in traditional breeding methods and the generation ofmutants,(see, for example, U.S. Pat. Nos. 5,162,602; 4,761,373;4,443,971). A1ternatively, novel plants with altered properties can begenerated with the aid of recombinant methods (see, for example,EP-A-0221044, EP-A-0131624). For example, the following have beendescribed in several cases:

the modification, by recombinant technology, of crop plants with the aimof modifying the starch synthesized in the plants (for example WO92/11376, WO 92/14827, WO 91/19806),

transgenic crop plants which exhibit resistances to other herbicides,for example to sulfonylureas (EP-A-0257993, US-A-5013659),

transgenic crop plants with the capability of producing Bacillusthuringiensis toxins (Bt toxins), which make the plants resistant tocertain pests (EP-A-0142924, EP-A-0193259),

transgenic crop plants with a modified fatty acid composition (WO91/13972).

A large number of techniques in molecular biology are known in principlewith the aid of which novel transgenic plants with modified propertiescan be generated: see, for example, Sambrook et al., 1989, MolecularCloning, A Laboratory Manual, 2nd Edition, Cold Spring Harbor LaboratoryPress, Cold Spring Harbor, N.Y.; or Winnacker “Gene und Klone”, VCHWeinheim 2nd Edition 1996 or Christou, “Trends in Plant Science” 1(1996) 423-431).

To carry out such recombinant manipulations, nucleic acid moleculeswhich allow mutagenesis or sequence changes by recombination of DNAsequences can be introduced into plasmids. For example, theabovementioned standard methods allow base exchanges to be carried out,subsequences to be removed, or natural or synthetic sequences to beadded. To connect the DNA fragments to each other, adapters or linkersmay be added to the fragments.

For example, the generation of plant cells with a reduced activity of agene product can be achieved by expressing at least one correspondingantisense RNA, a sense RNA for achieving a cosuppression effect or byexpressing at least one suitably constructed ribosome which specificallycleaves transcripts of the abovementioned gene product.

To this end, it is possible to use, on the one hand, DNA molecules whichencompass the entire coding sequence of a gene product inclusive of anyflanking sequences which may be present, as well as DNA molecules whichonly encompass portions of the coding sequence, it being necessary forthese portions to be long enough to have an antisense effect on thecells. The use of DNA sequences which have a high degree of homology tothe encoding sequences of a gene product, but are not completelyidentical to them, is also possible.

When expressing nucleic acid molecules in plants, the proteinsynthesized can be localized in any desired compartment of the plantcell. However, to achieve localization in a particular compartment, itis possible, for example, to link the coding region with DNA sequenceswhich ensure localization in a particular compartment. Such sequencesare known to those skilled in the art (see, for example, Braun et al.,EMBO J. 11 (1992), 3219-3227; Wolter et al., Proc. Natl. Acad. Sci. USA85 (1988), 846-850; Sonnewald et al., Plant J.1 (1991), 95-106).

The transgenic plant cells can be regenerated by known techniques togive rise to intact plants. In principle, the transgenic plants can beplants of any desired plant species, i.e. not only monocotyledonous, butalso dicotyledonous, plants. Thus, transgenic plants can be obtainedwhose properties are altered by overexpression, suppression orinhibition of homologous (=natural) genes or gene sequences or theexpression of heterologous (=foreign) genes or gene sequences.

The invention therefore also relates to a method of controllingundesired-vegetation (e.g. harmful plants), preferably in plant cropssuch as cereals (e.g. wheat, barley, rye, oats, hybrids thereof, such astriticale, rice, corn, panic grasses), sugar beet, sugar cane, oilseedrape, cotton and soya beans, preferably in corn, which comprisesapplying, together or separately, for example pr6-emergence,post-emergence or pre- and post-emergence, one or more herbicides oftype (A) together with one or more herbicides of type (B) and one ormore herbicides of type (C), to the plants, e.g. the harmful plants,parts of these plants, seeds of these plants, or the area on which theplants grow, for example the area under cultivation.

The plant crops can also have been genetically modified or been obtainedby mutation/selection and are preferably tolerant to acetolactatesynthase (ALS) inhibitors.

The invention also relates to the use of the novel combinations ofcompounds (A)+(B)+(C) for controlling harmful plants, preferably inplant crops.

The active ingredient combinations according to the invention can existnot only as mixed formulations of the components (A), (B) and (C), ifappropriate together with further agrochemically active ingredients,additives and/or customary formulation auxiliaries, which are thenapplied in the customary manner as a dilution with water, but also asso-called tank mixes by jointly diluting the separately formulated, orpartially separately formulated, components with water.

The compounds (A), (B) and (C) or their combinations can be formulatedin various ways, depending on the prevailing biological and/orchemical-physical parameters. The following are examples of generalpossibilities for formulations: wettable powders (WP), water-solubleconcentrates, emulsifiable concentrates (EC), aqueous solutions (SL),emulsions (EW) such as oil-in-water and water-in-oil emulsions,sprayable solutions or emulsions, suspension concentrates (SC), oil- orwater-based dispersions, suspoemulsions, dusts (DP), seed-dressingmaterials, granules for soil application or for broadcasting, orwater-dispersible granules (WG), ULV formulations, microcapsules orwaxes.

The individual formulation types are known in principle and aredescribed for example, in: Winnacker-Küchler, “Chemische Technologie”,Volume 7, C. Hauser Verlag Munich, 4th Edition, 1986; van Valkenburg,“Pesticide Formulations”, Marcel Dekker N.Y., 1973; K. Martens, “SprayDrying Handbook”, 3rd Ed. 1979, G. Goodwin Ltd. London.

The formulation auxiliaries required, such as inert materials,surfactants, solvents and other additives are also known and aredescribed, for example, in Watkins, “Handbook of Insecticide DustDiluents and Carriers”, 2nd Ed., Dariand Books, Caldwell N.J.; H.v.Olphen, “Introduction to Clay Colloid Chemistry”; 2nd Ed., J. Wiley &Sons, N.Y. Marsden, “Solvents Guide”, 2nd Ed., Interscience, N.Y. 1950;McCutcheon's, “Detergents and Emulsifiers Annual”, MC Publ. Corp.,Ridgewood N.J.; Sisley and Wood, “Encyclopedia of Surface ActiveAgents”, Chem. Publ. Co. Inc., N.Y. 1964; Schonfeldt,“Grenzflachenaktive Athylenoxidaddukte” [Surface-active ethylene oxideadducts], Wiss. Verlagsgesellschaft, Stuttgart 1976, Winnacker-Kuchler,“Chemische Technologie”, Volume 7, C. Hauser Verlag Munich, 4th Edition1986.

Based on these formulations, combinations with other pesticidally activesubstances, such as other herbicides, fungicides or insecticides, andwith safeners, fertilizers and/or growth regulators, may also beprepared, for example in the form of a readymix or a tank mix.

Wettable powders (sprayable powders) are products which are uniformlydispersible in water and which, besides the active ingredient, alsocomprise ionic or nonionic surfactants (wetters, dispersants), forexample polyoxethylated alkylphenols, polyethoxylated fatty alcohols orfatty amines, alkanesulfonates or alkylbenzenesulfonates, sodiumlignosulfonate, sodium 2,2′-dinaphthylmethane-6,6′-disulfonate, sodiumdibutyinaphthalenesulfonate or else sodium oleoylmethyltauride, inaddition to a diluent or inert material.

Emulsifiable concentrates are prepared by dissolving the activeingredient in an organic solvent, for example butanol, cyclohexanone,dimethylformamide, xylene or else higher-boiling aromatics orhydrocarbons with addition of one or more ionic or nonionic surfactants(emulsifiers). Examples of emulsifiers which may be used are: calciumsalts of alkylarylsulfonic acids, such as calcium dodecylbenzenesulfonate, or nonionic emulsifiers such as fatty acid polyglycol esters,alkylaryl polyglycol ethers, fatty alcohol polyglycol ethers, propyleneoxide/ethylene oxide condensates, alkyl polyethers, sorbitan fatty acidesters, polyoxyethylene sorbitan fatty acid esters or polyoxethylenesorbitol esters.

Dusts are obtained by grinding the active ingredient with finely dividedsolid materials, for example talc, natural clays such as kaolin,bentonite and pyrophyllite, or diatomaceous earth.

Suspension concentrates (SC) can be water- or oil-based. They can beprepared, for example, by wet grinding by means of commerciallyavailable bead mills and, if appropriate, addition of furthersurfactants as they have already been mentioned for example above in thecase of the other formulation types.

Emulsions, for example oil-in-water emulsions (EW), can be prepared forexample by means of stirrers, colloid mills and/or static mixers usingaqueous organic solvents and, if appropriate, further surfactants ashave already been mentioned for example above in the case of the otherformulation types.

Granules can be prepared either by spraying the active ingredient ontoadsorptive, granulated inert material or by applying active ingredientconcentrates to the surface of carriers such as sand, kaolites orgranulated inert material with the aid of binders, for example polyvinylalcohol, sodium polyacrylate or else mineral oils. Suitable activeingredients may also be granulated in the manner conventionally used forthe production of fertilizer granules, if desired in a mixture withfertilizers. As a rule, water-dispersible granules are prepared byconventional processes such as spray drying, fluidized-bed granulation,disk granulation, mixing with high-speed mixers and extrusion withoutsolid inert material. Regarding the production of disk granules,fluidized-bed granules, extruder granules and spray granules, see, forexample, the methods in “Spray-Drying Handbook” 3rd ed. 1979, G. GoodwinLtd., London; J. E. Browning, “Agglomeration”, Chemical and Engineering1967, page 147 et seq; “Perry's Chemical Engineer's Handbook”, 5th Ed.,McGraw-Hill, New York 1973, pp. 8-57.

As regards further details on the formulation of crop protectionproducts, see, for example, G. C. Klingman, “Weed Control as a Science”,John Wiley and Sons, Inc., New York, 1961, pages 81-96 and J. D. Freyer,S. A. Evans, “Weed Control Handbook”, 5th Ed., Blackwell ScientificPublications, Oxford, 1968, pages 101-103.

As a rule, the agrochemical formulations comprise 0.1 to 99 percent byweight, in particular 2 to 95% by weight, of active ingredients of thetypes A, B and/or C, the following concentrations being customary,depending on the type of formulation: The active ingredientconcentration in wettable powders is, for example, approximately 10 to95% by weight, the remainder to 100% by weight being composed ofcustomary formulation constituents. In the case of emulsifiableconcentrates, the active ingredient concentration may amount to, forexample, 5 to 80% by weight. Formulations in the form of dusts comprise,in most cases, 5 to 20% by weight of active ingredient, sprayablesolutions approximately 0.2 to 25% by weight of active ingredient.

In the case of granules such as dispersible granules, the activeingredient content depends partly on whether the active compound ispresent in liquid or solid form and on which granulation auxiliaries andfillers are being used. As a rule, the content amounts to between 10 and90% by weight in the case of the water-dispersible granules.

In addition, the abovementioned active ingredient formulations maycomprise, if appropriate, the conventional adhesives, wetters,dispersants, emulsifiers, preservatives, antifreeze agents, solvents,fillers, colorants, carriers, antifoams, evaporation inhibitors, pHregulators or viscosity regulators. The herbicidal activity of theherbicide combinations according to the invention can be improved, forexample by surface-active substances, preferably by wetting agents fromthe series of the fatty alcohol polyglycol ethers. The fatty alcoholpolyglycol ethers preferably have 10-18 carbon atoms in the fattyalcohol residue and 2-20 ethylene oxide units in the polyglycol ethermoiety. The fatty alcohol polyglycol ethers may exist in nonionic formor else in ionic form, for example in the form of fatty alcoholpolyglycol ether sulfates, which are used, for example, in the form ofthe alkali metal salts (for example the sodium and potassium salts) orthe ammonium salts, or else in the form of the alkaline earth metalsalts, such as magnesium salts, such as the sodium salt of C₁₂/C₁₄-fattyalcohol diglycol ether sulfate (Genapol® LRO, Clariant GmbH); see, forexample, EP-A-0476555, EP-A-0048436, EP-A-0336151 or U.S. Pat. No.4,400,196 and Proc. EWRS Symp. “Factors affecting herbicidal activityand selectivity”, 227-232 (1988). Examples of non-ionic fatty alcoholpolyglycol ethers are (C₁₀-C₁₈), preferably (C₁₀-C₁₄)-fatty alcoholpolyglycol ethers which contain 2-20, preferably 3-15, ethylene oxideunits (for example isotridecyl alcohol polyglycol ether), such as

Genapol® X-030, Genapol® X-060, Genapol® X-080 or Genapol® X-150 (all byClariant GmbH).

The present invention furthermore encompasses the combination ofherbicides (A), (B) and (C) with the abovementioned wetting agents fromthe series of the fatty alcohol polyglycol ethers which preferablycontain 10-18 carbon atoms in the fatty alcohol residue and 2-20ethylene oxide units in the polyglycol ether moiety and which can bepresent in nonionic or ionic form (for example in the form of the fattyalcohol polyglycol ether sulfates). Preferred are the sodium salt ofC₁₂/C14-fatty alcohol diglycol ether sulfate (Genapol® LRO, ClariantGmbH) and isotridecyl alcohol polyglycol ethers having 3-15 ethyleneoxide units, for example from the Genapol® X series, such as Genapol®X-030, Genapol® X-060, Genapol(® X-080 and Genapol® X-150 (all byClariant GmbH). It is furthermore known that fatty alcohol polyglycolethers such as nonionic or ionic fatty alcohol polyglycol ethers (forexample fatty alcohol polyglycol ether sulfates) are also suitable aspenetrants and synergists for a series of other herbicides, inter aliaalso for herbicides from the series of the imidazolinones (see, forexample, EP-A-0502014).

The herbicidal activity can also be increased by using vegetable oils.The term vegetable oils is to be understood as meaning oils fromoil-plant species, such as soya oil, rapeseed oil, corn oil, sunfloweroil, cottonseed oil, linseed oil, coconut oil, palm oil, safflower oilor castor oil, in particular rapeseed oil, and their transesterificationproducts, for example alkyl esters, such as rapeseed oil methyl ester orrapeseed oil ethyl ester.

The vegetable oils are preferably esters of C₁₀-C₂₂-, preferablyC₁₂-C₂₀-fatty acids. The C₁₀-C₂₂-fatty acid esters are, for example,esters of unsaturated or saturated C₁₀-C₂₂-fatty acids, in particularthose with an even number of carbon atoms, for example erucic acid,lauric acid, palmitic acid and, in particular, C₁₈-fatty acids such asstearic acid, oleic acid, linoleic acid or linolenic acid.

Examples of C₁₀-C₂₂-fatty acid esters are esters obtained by reactingglycerol or glycol with the C₁₀-C₂₂-fatty acids as they exist, forexample, in oils from oil-plant species, or C₁-C₂₀-alkyl-C₁₀-C₂₂-fattyacid esters as can be obtained, for example, by transesterification ofthe abovementioned glycerol- or glycol-C₁₀-C₂₂-fatty acid esters withC₁-C₂₀-alcohols (for example methanol, ethanol, propanol or butanol).Transesterification can be carried out by known methods as aredescribed, for example, in Rompp Chemie Lexikon, 9th Edition, Volume 2,page 1343, Thieme Verlag Stuttgart.

Preferred C₁-C₂₀-alkyl-C₁₀-C₂₂-fatty acid esters are the methyl, ethyl,propyl, butyl, 2-ethylhexyl and dodecyl esters. Preferred glycol- andglycerol-C₁₀-C₂₂-fafty acid esters are the uniform or mixed glycolesters and glycerol esters of C₁₀-C₂₂-fatty acids, in particular ofthose fatty acids which have an even number of carbon atoms, for exampleerucic acid, lauric acid, palmitic acid and, in particular, C₁₈-fattyacids such as stearic acid, oleic acid, linolic acid or linolenic acid.

The vegetable oils can be present in the herbicidal compositionsaccording to the invention for example in the form of commerciallyavailable oil-containing formulation additives, in particular thosebased on rapeseed oil such as Hasten® (Victorian Chemical Company,Australia, hereinbelow termed Hasten, main constituent: rapeseed oilethyl ester), Actirob®B (Novance, France, hereinbelow termed ActirobB,main constituent: rapeseed oil methyl ester), Rako-Binol® (Bayer AG,Germany, termed Rako-Binol hereinbelow, main constituent: rapeseed oil),Renol® (Stefes, Germany, termed Renol hereinbelow, vegetable oilconstituent: rapeseed oil methyl ester), or Stefes Mero® (Stefes,Germany, hereinbelow termed Mero, main constituent: rapeseed oil methylester).

In a further embodiment, the present invention encompasses combinationsof herbicides (A), (B) and (C) with the abovementioned vegetable oils,such as rapeseed oil, preferably in the form of commercially availableoil-containing formulation additives, in particular those which arebased on rapeseed oil, such as Hasten® (Victorian Chemical Company,Australia, hereinbelow referred to as Hasten, main constituent: rapeseedoil ethyl ester), Actirob®B (Novance, France, hereinbelow referred to asActirobB, main constituent: rapeseed oil methyl ester), Rako-Bino®(Bayer AG, Germany, hereinbelow referred to a Rako-Binol, mainconstituent: rapeseed oil), Renol® (Stefes, Germany, hereinbelowreferred to a Renol, vegetable oil constituent: rapeseed oil methylester) or Stefes Mero® (Stefes, Germany, hereinbelow referred to asMero, main constituent: rapeseed oil methyl ester).

For use, the formulations, which are present in commercially availableform, are optionally diluted in the customary manner, for example usingwater in the case of wettable powders, emulsifiable concentrates,dispersions and water-dispersible granules. Preparations in the form ofdusts, soil granules, granules for broadcasting and sprayable solutionsare usually not diluted further with other inert substances prior touse.

The active ingredients can be applied to the plants, parts of theplants, seeds of the plants or the area under cultivation (soil of afield), preferably to the green plants and parts of the plants and, ifappropriate, additionally to the soil of the field. One possible use isthe joint application of the active ingredients in the form of tankmixes, the concentrated formulations of the individual activeingredients, in optimal formulations, jointly being mixed with water inthe tank and the resulting spray mixture being applied.

A joint herbicidal formulation of the combination according to theinvention of the active ingredients (A), (B) and (C) has the advantageof being easier to apply since the quantities of the components arealready presented in the correct ratio to each other. Moreover, theadjuvants in the formulation can be matched optimally to each other.

A. General formulation examples

a) A dust is obtained by mixing 10 parts by weight of an activeingredient/active ingredient mixture and 90 parts by weight of talc asinert material and comminuting the mixture in a hammer mill.

b) A wettable powder which is readily dispersible in water is obtainedby mixing 25 parts by weight of an active ingredient/active ingredientmixture, 64 parts by weight of kaolin-containing quartz as inertmaterial, 10 parts by weight of potassium lignosulfonate and 1 part byweight of sodium oleoylmethyltaurinate as wetter and dispersant, andgrinding the mixture in a pinned-disk mill.

c) A dispersion concentrate which is readily dispersible in water isobtained by mixing 20 parts by weight of an active ingredient/activeingredient mixture with 6 parts by weight of alkylphenol polyglycolether (® Triton X 207), 3 parts by weight of isotridecanol polyglycolether (8 EO) and 71 parts by weight of paraffinic mineral oil (boilingrange for example approx. 255 to 277° C), and grinding the mixture in aball mill to a fineness of below 5 microns.

d) An emulsifiable concentrate is obtained from 15 parts by weight of anactive ingredient/active ingredient mixture, 75 parts by weight ofcyclohexanone as solvent and 10 parts by weight of oxethylatednonylphenol as emulsifier.

e) Water-dispersible granules are obtained by mixing

75 parts by weight of an active ingredient/active ingredient mixture,

10 parts by weight of calcium lignosulfonate,

5 parts by weight of sodium lauryl sulfate,

3 parts by weight of polyvinyl alcohol and

7 parts by weight of kaolin,

grinding the mixture on a pinned-disk mill and granulating the powder ina fluidized bed by spraying on water as granulation liquid.

f) Water-dispersible granules are also obtained by homogenizing andprecomminuting, in a colloid mill,

25 parts by weight of an active ingredient/active ingredient mixture,

5 parts by weight of sodium 2,2′-dinaphthylmethane-6,6′-disulfonate,

2 parts by weight of sodium oleoylmethyltaurinate,

1 part by weight of polyvinyl alcohol,

17 parts by weight of calcium carbonate and

50 parts by weight of water,

subsequently grinding the mixture in a bead mill and atomizing anddrying the resulting suspension in a spray tower by means of asingle-substance nozzle.

B. Biological Examples

Herbicidal action (field trials)

The seeds or rhizome pieces of typical harmful plants were planted andgrown under natural field conditions. Before the harmful plants hademerged or after the harmful plants had emerged, they were treated, as arule at the 2- to 8-leaf stage, with various dosages of the compositionsaccording to the invention at a water application rate of 100 to 400I/ha (converted).

After the treatment (approx. 4-6 weeks after application), theherbidical activity of the active ingredients or active ingredientmixtures was scored visually by comparing the treated plots with theuntreated control plots. Damage and development of all aerial parts ofthe plants was recorded. Scoring was done on a percentage scale (100%action=all plants dead; 50% action=50% of the plants and green plantparts dead; 0% action=no discernible action=like control plot). Thescore figures of in each case 4 plots was averaged.

The results are shown in the tables which follow, the action when usingactive ingredients (A+B) and (C) independently being stated in brackets.

Maize Sorghum % verticillata g As/ha damage % activity (A + B) (A1 +B2)^(s) 45 + 1.5 0  0 C) metochlor (C3) + 1200 + 625 0 75 atrazine (C7)(A + B) + (45 + 1.5) + 0 97 (75 + 0) C) (1200 + 625) D) nicosulfuron(C15)  60 0 74 (A + B) + (45 + 1.5) + 0 95 (0 + 74) D)  60 MaizePolygonum % convolvulus g As/ha damage % activity (A + B) (A1 + B2)^(s)45 + 5 3 56 E) bromoxynil (C33) 240 2 40 (A + B) + (45 + 5) + 15 98(56 + E) 240 40) F) dicamba (C20)  60 0 35 (A + B) + (15 + 5) + 0 95(56 + F)  60 35) Maize Setaria % spp. g As/ha damage % activity (A + B)(A1 + B2)^(s) 45 + 5 8 79 G) halosulfuron (C40)  36 3 0 (A + B) + (45 +5) + 7 87 (79 + 0) G)  36 H) prosulfuron (C42)  40 7 15 (A + B) + (45 +5) + 8 95 (79 + H) 40 15) Abbreviations: g AS/ha = application rate ingrams of active substance per hectare (A1 + B2)^(s) = foramsulfuron +odosulfuron-methyl-sodium + isoxadifen-ethyl (S1-9)

We claim:
 1. A herbicide combination with an effective content ofcomponents (A), (B) and (C), where (A) denotes one or more herbicidesfrom the group of the compounds of the formula (I) or their salts,

(B) denotes one or more herbicides from the group of the compounds ofthe formula (II) and their salts,

and (C) denotes one or more herbicides from the group of the compoundsconsisting of (C1) flumioxazin (C2) alachlor (C3) metolachlor (C4)acetochlor (C5) dimethenamid (C6) pethoxamid (C7) atrazine (C8) simazine(C9) cyanazine (C10) terbuthylazine (C11) metribuzin (C12) isoxaflutole(C13) fluthiamid (C14) terbutryne (C15) nicosulfuron (C16) rimsulfuron(C17) primsulfuron (C18) pendimethalin (C19) sulcotrione (C20) dicamba(C21) mesotrione (C22) linuron (C23) benoxacor (C24) metosulam (C25)flumetsulam (C26) sethoxydim (C27) cycloxydim (C28) clethodim (C29)clefoxidim (C30) aclonifen (C31) MCPA (C32) 2, 4-D (C33) bromoxynil(C34) bentazone (C35) fluthiacet (C36) pyridate (C37) diflufenzopyr(C38) carfentrazone (C39) clopyralid (C40) halosulfuron (C41)thifensulfuron (C42) prosulfuron (C43) tritosulfuron (C44) sulfosulfuron(C45) ethoxysulfuron (C46) tribenuron (C47) amidosulfuron (C48) mecoprop(C49) dichlorprop (C50) fluroxypyr (C51) profluazol (C52) amicarbazone(C53) trifloxysulfuron (C54) glufosinate (C55) glufosinate-ammonium(C56) glyphosate (C57) glyphosate-isopropylammonium (C58) imazapyr (C59)imazethapyr (C60) imazamethabenz (C61) imazamox (C62) imazaquin and(C63) imazapic (AC 263,222).


2. A herbicide combination as claimed in claim 1, which comprises, ascomponent (A), foramsulfuron, foramsulfuron-sodium or mixtures thereofand, as component (B), iodosulfuron-methyl, iodosulfuron-methyl-sodiumor mixtures thereof.
 3. A herbicide combination as claimed in claim 1,additionally comprising one or more further components from the groupconsisting of agrochemically active ingredients of a different type,formulation auxiliaries and additives conventionally used in cropprotection.
 4. A herbicide combination as claimed in claim 1,additionally comprising one or more safeners.
 5. A herbicide combinationas claimed in claim 1, which additionally comprises one or more fattyalcohol polyglycol esters, one or more vegetable oils or mixturesthereof.
 6. A method for controlling undesired vegetation, whichcomprises applying, jointly or separately, the herbicides (A), (B) and(C) as defined in claim 1 to the plants, plant parts, the seeds of theplants or the area on which the plants grow.
 7. The method as claimed inclaim 6 for the selective control of harmful plants in plant crops. 8.The method as claimed in claim 7 for the control of harmful plants incorn.
 9. The method as claimed in claim 7, wherein the plant crops aregenetically modified or obtained by mutation/selection.
 10. A method ofusing the herbicide combination of claim 1, comprising the step ofapplying the combination to a locus for controlling harmful plants.